Tri-n-butyltin deuteride 氘代三正丁基锡
CAS 6180-99-0 MFCD00064886
化学结构图
SMILES: CCCC[SnH](CCCC)CCCC
化学属性
| Mol. Formula | C12H27DSn |
|---|---|
| Mol. Weight | 292 |
| Density | 1.103 |
| Refractive index | 1.4720 |
| Flash Point | 40°(104°F) |
| TSCA | No |
| Boiling Point | 65°/0.6mm |
别名和识别编码
| Chemical Name | Tri-n-butyltin Deuteride |
|---|---|
| CAS Number | 6180-99-0 |
| Synonym | Tributyl-stannane-d Tributylhydro-d-tin Tributyldeuteriostannane Tributylstannyl Deuteride Tributyltin Deuteride Deutero tri-n-butylstannane |
| MDL Number | MFCD00064886 |
| EC Number | 211-704-4 |
| Beilstein Registry Number | 4126434 |
| Chemical Name Translation | 氘代三正丁基锡 |
| LabNetwork Molecule ID | LN01293032 |
| PubChem Substance ID | 2733350 |
| InChI | InChI=1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;/i;;;;1+1 |
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分类
- Isotope Labelled Compounds
- Miscellaneous Reagents
产品应用
- Dangerous for the environment.
相关文献及参考
- Reducing agent, cf Tri-n-butyltin hydride, A13298, providing a convenient means of preparing specifically-deuterated compounds from the corresponding halide.
- Used in combination with the catalyst derived from (R)- or (S)-BINOL and Ti(O-i-Pr)4 for the asymmetric reduction of aldehydes to chiral monodeutero primary alcohols (RCHDOH): J. Org. Chem., 61, 7638 (1996).
安全信息
- R10 Flammable 易燃
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R21 Harmful in contact with skin 与皮肤接触有害
- R48/23/25
- R25 Toxic if swallowed 吞咽有毒
- R50/53
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P316
- P302+P352
- P303+P361+P353
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P317
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P337+P313
- P337+P317
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H301 Toxic if swallowed 吞食有毒
- H312 Harmful in contact with skin 皮肤接触有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
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