2,2,2-Trifluoroethyl Trifluoromethanesulfonate 2,2,2-三氟乙基三氟甲烷磺酸酯

CAS 6226-25-1 MFCD00671579

化学结构图

6226-25-1
SMILES: O=S(=O)(OCC(F)(F)F)C(F)(F)F

化学属性

Mol. FormulaC3H2F6O3S
Mol. Weight232
Boiling Point>110
Density1.611
Refractive index1.3040 to 1.3070
Flash Point>110°(230°F)
TSCANo
Appearance 无色液体。

别名和识别编码

Chemical Name2,2,2-Trifluoroethyl Trifluoromethanesulfonate
CAS Number6226-25-1
Alfabeta NameTRIFLUOROETHYLTRIFLUOROMETHANESULFONATE 222-,,
MDL NumberMFCD00671579
Synonym 2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE 2,2,2-Trifluoroethyl trifluoromethanesulfonate 2,2,2-Trifluoroethyltrifluoromethanesulphonate97% 2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULFONATE 2,2,2-三氟乙基三氟甲烷磺酸酯 2,2,2-Trifluoroethanol Trifluoromethanesulfonate 2,2,2-三氟乙基三氟甲烷磺酸酯; 三氟甲磺酸三氟乙酯
Chemical Name Translation2,2,2-三氟乙基三氟甲烷磺酸酯
Reaxys-RN2051235
PubChem Substance ID80366
Beilstein Registry Number2051235
InChIKeyRTMMSCJWQYWMNK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009361
InChIInChI=1S/C3H2F6O3S/c4-2(5,6)1-12-13(10,11)3(7,8)9/h1H2
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分类

  • Pharmaceuticals
  • {SNA} Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents, Trifluoromethylation
  • Intermediates & Fine Chemicals
  • Sulfur & Selenium Compounds,

产品应用

  • A fluorine-containing alkyl alkanesulfonate with cyctotoxity towards cultured leukemia L1210 cells.

相关文献及参考

  • Ohta, Y. et al.: Chem. Pharmac. Bull., 36, 2410 (1988);

安全信息

Warnings TOXIC, CORROSIVE
Hazard Codes T Xi,T,C
WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P330+P331
  • P302+P352
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
RTECSPB2775000
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20 Harmful by inhalation 吸入有害
  • R34 Causes burns 会导致灼伤
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Packing GroupII
UN Number 2920 UN3265
Storage condition Moisture Sensitive
Hazard Class8/3
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 876 ppm/6H
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - other changes
   Blood - hemorrhage
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0530474-2

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0530474

其他信息

  • TCI Shanghai:三氟甲烷磺酸-2,2,2-三氟乙酯 2,2,2-Trifluoroethyl Trifluoromethanesulfonate,>;95.0%(GC)(6226-25-1)
  • Hazard Note:Irritant
  • 2,2,2-三氟乙基三氟甲烷磺酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1604 三氟甲烷磺酸2,2,2-三氟乙酯 2,2,2-Trifluoroethyl Trifluoromethanesulfonate 5G 1140元 2014/06/02 T1604 三氟甲烷磺酸2,2,2-三氟乙酯 2,2,2-Trifluoroethyl Trifluoromethanesulfonate 25G 3740元
  • MOL 文件:6226-25-1.mol

系列性分类


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