1,2-Diiodoethane 1,2-二碘乙烷

CAS 624-73-7 MFCD00001093

化学结构图

624-73-7
SMILES: ICCI

化学属性

Mol. FormulaC2H4I2
Mol. Weight281.86
Density2.13
Melting Point80-82 °C
TSCAYes
Appearance 黄色菱状或片状结晶。熔点83℃,沸点200℃,相对密度2.132(10℃),折光率1.871。溶于乙醇和乙醚,微溶于水。
Boiling Point200.05 °C at 760 mmHg

别名和识别编码

Chemical Name1,2-Diiodoethane
Synonym 1,2-Diiodoethane {LY} 1,2-Diiodoethane {} {LY} 1,2-Diiodoethane {} {} {LY} 1,2-Diiodoethane {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Diiodoethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00001093
CAS Number624-73-7
PubChem Substance ID87567604
EC Number210-859-5
Beilstein Registry Number1,99
Reaxys-RN1730870
Chemical Name Translation1,2-二碘乙烷
InChIKeyGBBZLMLLFVFKJM-UHFFFAOYSA-N
LabNetwork Molecule IDLN01741445
InChIInChI=1S/C2H4I2/c3-1-2-4/h1-2H2
Canonical SMILESICCI
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/27B
  • Short: II/25B
  • Source of positive iodine, for example in the formation of 2-iodoindole from lithiated indole-1-carbamate: J. Org. Chem., 57, 2495 (1992), and in the stereoselective formation of (Z)-2-iodoalk-2-enes from ß-oxido phosphonium ylides: J. Chem. Soc., Perkin 1, 1331 (1995).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light <0°C <;0 Air & Light Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xi
Packing GroupIII
Hazard Class6.1(b)
UN Number 2811

其他信息

  • MOL 文件:624-73-7.mol
  • 图谱信息:1,2-二碘乙烷(624-73-7)红外图谱(IR1) 1,2-二碘乙烷(624-73-7)核磁图( 13 CNMR) 1,2-二碘乙烷(624-73-7)红外图谱(IR2) 1,2-二碘乙烷(624-73-7)核磁图( 1 HNMR)
  • Sigma Aldrich:624-73-7(sigmaaldrich)
  • 用途一:用于有机合成。
  • F:8-9-23
  • Alfa Aesar:1,2-二碘代乙烷,98% 1,2-Diiodoethane, 98%(624-73-7)
  • Acros Organics:1,2-二碘乙烷 1,2-Diiodoethane, 99%(624-73-7)
  • 下游产品:2-溴-5-碘吡啶
  • 敏感性:Air & Light Sensitive
  • TCI Shanghai:1,2-二碘乙烷 1,2-Diiodoethane,>;95.0%(GC)(624-73-7)
  • 方法一:由乙烯与碘反应而得。将乙烯通入碘和乙醇的混合物中,直至碘的颜色完全消失而有针状结晶产生为止。反应完成后,过滤,洗涤,将所得粗品用乙醇重结晶,得1,2-二碘乙烷。
  • 1,2-二碘乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1025 1,2-二碘乙烷 1,2-Diiodoethane 25G 473元 2010/06/21 115140250 1,2-二碘乙烷 1,2-Diiodoethane 99% 25 GR 566元 2010/06/21 115141000 1,2-二碘乙烷 1,2-Diiodoethane 99% 100 GR 2294元

系列性分类


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