3-Bromothiophenol, 98% 3-溴苯硫醇

CAS 6320-01-0 MFCD00009603

化学结构图

6320-01-0
SMILES: Sc1cccc(Br)c1

化学属性

Mol. FormulaC6H5BrS
Mol. Weight189.07
Boiling Point123-124 °C at 40 mmHg
Density1.832 g/mL at 25 °C(lit.)
Refractive index1.6310 to 1.6360
Flash Point105°C(lit.)
TSCANo
Stability对空气敏感
Melting Point214-215 °C

别名和识别编码

Chemical Name3-Bromothiophenol, 98%
CAS Number6320-01-0
Alfabeta NameBROMOTHIOPHENOL 3-
MDL NumberMFCD00009603
Synonym 3-Bromothiophenol {LY} 3-Bromothiophenol {} {LY} 3-Bromothiophenol {} {} {LY} 3-Bromothiophenol {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromothiophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number228-664-9
Beilstein Registry Number6(4)1648
PubChem Substance ID80597
Reaxys-RN1926242
Chemical Name Translation3-溴苯硫醇
InChIKeyHNGQQUDFJDROPY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007964
InChIInChI=1S/C6H5BrS/c7-5-2-1-3-6(8)4-5/h1-4,8H
Canonical SMILESSC1=CC=CC(Br)=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; thiol; 1fragment

产品应用

  • 医药中间体。

相关文献及参考

  • Short: II/27B
  • Short: EINECS
  • Beilstein:6(4)1648

安全信息

Warnings TOXIC, STENCH, CORROSIVE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R25 Toxic if swallowed 吞咽有毒
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Packing GroupIII
UN Number UN2922 1760 2811
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive Refrigerator {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Hazard Class8

其他信息

  • 3-溴苯硫酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2348 3-溴苯硫酚 3-Bromobenzenethiol 5G 1100元 2014/06/02 B2348 3-溴苯硫酚 3-Bromobenzenethiol 25G 3400元 2010/06/21 303710050 3-溴苯硫酚 3-Bromothiophenol 95% 5 GR 1072元
  • 用途一:医药中间体。
  • Acros Organics:3-Bromothiophenol, 95%(6320-01-0)
  • F:10-13-23
  • Alfa Aesar:3-溴苯硫酚,97% 3-Bromothiophenol, 97%(6320-01-0)
  • Hazard Note:Irritant/Stench
  • MOL 文件:6320-01-0.mol
  • 检测方法:HPLC
  • Sigma Aldrich:6320-01-0(sigmaaldrich)
  • 上游原料:稀硫酸 --> 间溴苯胺 --> 乙基黄原酸钾 --> 苯胺酸
  • 敏感性:Stench
  • 方法一:由间溴苯胺盐酸经重氮化、置换而得。将间溴苯胺酸盐、水加入反应锅，搅拌下慢慢滴加浓盐酸使全部溶解。冷却至0℃左右，缓缓滴加亚硝酸钠溶液，加毕，保温0.5h，得间溴苯胺重氮化溶液备用。另将乙基黄原酸钾水溶液加入反应锅，加热至45-50℃，缓缓加入重氮液，加毕，保温0.5h。用苯提取，提取液回收苯后，加入乙醇和氢氧化钾搅拌回流7h，回收乙醇至干，用3.6倍量的水使全部溶解，以稀硫酸调节pH至4，过滤，用苯提取，回收苯，减压蒸馏，收集120℃（2.93kPa）馏分而得成品。
  • TCI Shanghai:3-溴苯硫酚 3-Bromobenzenethiol,>;98.0%(GC)(6320-01-0)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts

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