ETHYL AZIDOACETATE 叠氮乙酸乙酯

CAS 637-81-0 MFCD00190177

化学结构图

637-81-0
SMILES: CCOC(=O)CN=[N+]=[N-]

化学属性

Mol. FormulaC4H7N3O2
Mol. Weight129
Flash Point7 ºC
Boiling Point164°C(lit.)
Density1.120000

别名和识别编码

Chemical NameETHYL AZIDOACETATE
Beilstein Registry Number4247209
PubChem Substance ID69480
CAS Number637-81-0
MDL NumberMFCD00190177
EC Number211-301-3
Synonym ETHYL AZIDOACETATE SOLUTION, 25% IN ETHANOL 叠氮乙酸乙酯 溶液 ETHYL AZIDOACETATE SOLUTION, 25% IN TOLUENE Ethyl azidoacetate, GC 98% Ethyl azidacetate 97% Azidoacetic acid ethyl ester azido-aceticaciethylester ETHYL AZIDOACETATE AZIDOACETIC-ACID-ETHYL-ESTER ETHYLAZIDACETATE ethyl azidoacetate solution 叠氮乙酸乙酯 ETHYL AZIDOACETATE SOLUTION, 30% IN METHYLENECHLORIDE 2-Azidoacetic acid ethyl ester
Chemical Name Translation叠氮乙酸乙酯
InChIKeyHVJJYOAPXBPQQV-UHFFFAOYSA-N
LabNetwork Molecule IDLN00226109
Reaxys-RN1099789
InChIInChI=1S/C4H7N3O2/c1-2-9-4(8)3-6-7-5/h2-3H2,1H3
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分类

  • {SNA} Aliphatic Azides, Azides, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Aliphatic Azides, Azides, Building Blocks, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Copper Click Chemistry, Nitrogen Compounds, Organic Azides, Organic Building Blocks
  • Aliphatic Azides, Azides, Building Blocks, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Nitrogen Compounds, Organic Azides, Organic Building Blocks
  • {SNA} Aliphatic Azides,

安全信息

Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Danger Warning
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Hazard Codes Xn F,Xn Xn,Xi,C Xi
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S7 Keep container tightly closed 保存在严格密闭容器中;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S47 Keep at temperature not exceeding ... °C (to be specified by the manufacturer) 保持温度不超过……°C(由生产厂家指定);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
Risk Statements
  • R1 Explosive when dry 干燥时易爆
  • R10 Flammable 易燃
  • R48/20
  • R11 Highly flammable 非常易燃
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R38 Irritating to skin 刺激皮肤
UN Number 1294 1993 UN 1593 6.1/PG 3
RTECSAF4340000
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 20 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 216,27,1989

Hazard Class3
Storage condition 0-10°C
Packing GroupIII

其他信息

  • MOL 文件:637-81-0.mol
  • 下游产品:2-羰基-4甲氧基-7-氮杂吲哚 --> 2-甲醇-4-甲氧基-7-氮杂吲哚 --> 5-苄氧基-4-氮杂吲哚-2-羧酸
  • Hazard Note:Irritant/Corrosive
  • Sigma Aldrich:637-81-0(sigmaaldrich)

系列性分类


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