5-Amino-2-methoxypyridine 5-氨基-2-甲氧基吡啶

CAS 6628-77-9 MFCD00006264

化学结构图

6628-77-9
SMILES: COc1ccc(N)cn1

化学属性

Mol. FormulaC6H8N2O
Mol. Weight124.14
Melting Point29-31°C
Density1.575
Refractive indexn20/D 1.575(lit.)
Boiling Point264.8°C at 760 mmHg
Flash Point>110°(230°F)
TSCANo
SolubilitySlightly soluble

别名和识别编码

Chemical Name5-Amino-2-methoxypyridine
CAS Number6628-77-9
Alfabeta NameAMINOMETHOXYPYRIDINE 52---
MDL NumberMFCD00006264
EC Number229-612-8
Beilstein Registry Number22(5)11,408
PubChem Substance ID81121
Synonym 5-Amino-2-methoxypyridine {LY} 5-Amino-2-methoxypyridine {} {LY} 5-Amino-2-methoxypyridine {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation5-氨基-2-甲氧基吡啶
Reaxys-RN115155
InChIKeyUUVDJIWRSIJEBS-UHFFFAOYSA-N
Wiswesser Line NotationT6NJ BO1 EZ
LabNetwork Molecule IDLN00140549
InChIInChI=1S/C6H8N2O/c1-9-6-3-2-5(7)4-8-6/h2-4H,7H2,1H3
Canonical SMILESCOC(C=C1)=NC=C1N
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSUS1836000
Hazard Codes Xn Xn,Xi
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 89,153,1947

其他信息

  • 用途三:医药中间体,用于生产咯萘啶磷酸盐
  • Sigma Aldrich:6628-77-9(sigmaaldrich)
  • 上游原料:乙醇 --> 甲醇 --> 氢化钠 --> 铁粉 --> 亚硫酸钠 --> 连二亚硫酸钠 --> 2-氯-5-硝基吡啶 --> 5-硝基-2-甲氧基吡啶
  • 用途二:医药中间体。用于生产咯萘啶磷酸盐。
  • Acros Organics:5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine, tech., 90%(6628-77-9)
  • 用途一:用作药物中间体
  • Hazard Note:Irritant
  • MOL 文件:6628-77-9.mol
  • 方法一:由2-甲氧基-5-硝基吡啶还原而得。将50%甲醇、铁粉及乙酸加热至回流，分次加入2-甲氧基-5-硝基吡啶，回流4h。用20%氢氧化钠液碱化，过滤，滤液减压蒸馏，收集140-142℃（3.33-3.60kPa）馏分，得5-氨基-5-甲氧基吡啶。收率70%。
  • TCI Shanghai:5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine,>;98.0%(GC)(6628-77-9)
  • Alfa Aesar:5-氨基-2-甲氧基吡啶,98% 5-Amino-2-methoxypyridine, 98%(6628-77-9)
  • 检测方法:HPLC,NMR
  • MSDS 信息:6-Methoxy-3-pyridylamine(6628-77-9).msds
  • 下游产品:5-氨基-2-甲氧基吡啶-4-羧酸 --> 3-氨基-6-甲氧基-2-氯吡啶 --> 5-氟-2-甲氧基吡啶-4-硼酸
  • 5-氨基-2-甲氧基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1956 5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine 25G 1380元 2014/06/02 A1956 5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine 5G 449元 2010/06/21 103951000 5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine 90%, tech. 100 GR 6039元

系列性分类

  1. C6 - Pyridines
  1. C6 to C7 - Pyridines
  1. C5
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

相关产品推荐