2-Hydroxy-4-Methoxybenzaldehyde 2-羟基-4-甲氧基苯甲醛

CAS 673-22-3 MFCD00003327

化学结构图

673-22-3
SMILES:

化学属性

Mol. FormulaC8H8O3
Mol. Weight152.15
Melting Point41-43°C
Density1.231
Flash Point113°C
TSCAYes
Boiling Point271.5°C at 760 mmHg
Appearance 白色结晶体。熔点42-43℃。

别名和识别编码

Chemical Name2-Hydroxy-4-Methoxybenzaldehyde
CAS Number673-22-3
Alfabeta NameHYDROXYMETHOXYBENZALDEHYDE 24---
MDL NumberMFCD00003327
Synonym 2-Hydroxy-4-methoxybenzaldehyde {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Hydroxy-4-methoxybenzaldehyde {} {} {} {
PubChem Substance ID87571067
EC Number211-604-0
Beilstein Registry Number1072443
Reaxys-RN1072443
Chemical Name Translation2-羟基-4-甲氧基苯甲醛
InChIKeyWZUODJNEIXSNEU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00174211
Canonical SMILESO=CC1=CC=C(OC)C=C1O
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分类

  • Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {SNA} Aldehydes, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

产品应用

  • 用作有机合成中间体。

相关文献及参考

  • [2]. Kubo I, et al. 2-Hydroxy-4-methoxybenzaldehyde: a potent tyrosinase inhibitor from African medicinal plants. Planta Med. 1999 Feb;65(1):19-22.
  • Beilstein:8,242
  • Condensation with t-butyl acrylate results in cyclization to t-butyl 7-methoxychromene-3-carboxylate: J. Med. Chem., 36, 3580 (1993):
  • With (Ethoxycarbonyl­methyl­ene)­triphenyl­phosphorane, A12896, in N,N-diethylaniline cyclization to 7-methoxycoumarin occurs: Heterocycles, 39, 613 (1994).
  • [1]. Bodwell Graham, et al. An Inverse Electron-Demand Diels-Alder-Based Total Synthesis of Urolithin M7. Synlett. 2011 (15): 2245.
  • [1]. Bodwell Graham, et al. An Inverse Electron-Demand Diels-Alder-Based Total Synthesis of Urolithin M7. Synlett. 2011 (15): 2245.
  • [2]. Kubo I, et al. 2-Hydroxy-4-methoxybenzaldehyde: a potent tyrosinase inhibitor from African medicinal plants. Planta Med. 1999 Feb;65(1):19-22.

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
RTECSBZ2810000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S26/36
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8° 
TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 206,17,1988

其他信息

  • 图谱信息:2-羟基-4-甲氧基苯甲醛(673-22-3)红外图谱(IR1) 2-羟基-4-甲氧基苯甲醛(673-22-3)红外图谱(IR2) 2-羟基-4-甲氧基苯甲醛(673-22-3)质谱(MS)
  • 用途三:用作有机合成中间体。
  • 海关编码:29124900
  • 下游产品:
  • Alfa Aesar:2-羟基-6-甲氧基苯甲醛,98+% 2-Hydroxy-6-methoxybenzaldehyde, 98+%(700-44-7)
  • Hazard Note:Irritant
  • TCI Shanghai:2-羟基-4-甲氧基苯甲醛 2-Hydroxy-4-methoxybenzaldehyde,>;97.0%(T)(673-22-3)
  • 敏感性:Air Sensitive
  • F:10
  • Sigma Aldrich:700-44-7(sigmaaldrich)
  • Alfa Aesar:2-羟基-4-甲氧基苯甲醛,99% 2-Hydroxy-4-methoxybenzaldehyde, 99%(673-22-3)
  • Acros Organics:2-羟基-4-甲氧基苯甲醛/4-甲氧基水杨醛 2-Hydroxy-4-methoxybenzaldehyde, 99%(673-22-3)
  • MSDS 信息:2-Hydroxy-4-methoxybenzaldehyde(673-22-3).msds
  • 用途二:医药中间体。
  • 检测方法:HPLC
  • 用途一:用作有机合成中间体
  • 2-羟基-4-甲氧基苯甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L13145 2-羟基-6-甲氧基苯甲醛, 98+% 2-Hydroxy-6-methoxybenzaldehyde, 98+% 5g 2352元 2010/05/25 L13145 2-羟基-6-甲氧基苯甲醛, 98+% 2-Hydroxy-6-methoxybenzaldehyde, 98+% 1g 612元
  • Sigma Aldrich:673-22-3(sigmaaldrich)
  • MOL 文件:673-22-3.mol
  • 2-羟基-4-甲氧基苯甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0699 2-羟基-4-甲氧基苯甲醛 2-Hydroxy-4-methoxybenzaldehyde 5G 579元 2014/06/02 H0699 2-羟基-4-甲氧基苯甲醛 2-Hydroxy-4-methoxybenzaldehyde 25G 1790元 2010/06/21 171080050 2-羟基-4-甲氧基苯甲醛 2-Hydroxy-4-methoxybenzaldehyde 99% 5 GR 671元
  • MOL 文件:700-44-7.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes - Carbonyl Compounds
  6. C8 - Aldehydes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic aldehyde<including acetal,hemiacetal>
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aldehydes
  6. C7
  1. Medical Research Areas
  2. Metabolism
  3. Tyrosinase  (酪氨酸酶)

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