1,1-Bis(tert-Butylperoxy)-3,3,5-trimethylcyclohexane 1,1-双(叔丁基过氧基)-3,3,5-三甲基环己烷

CAS 6731-36-8 MFCD00084801

化学结构图

6731-36-8
SMILES: CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1

化学属性

Mol. FormulaC17 H34 O4
Mol. Weight302.45
Refractive indexn20/D 1.441(lit.)
Density0.895
Melting Point-20
Flash Point62 ºC
Solubility不溶

别名和识别编码

Chemical Name1,1-Bis(tert-Butylperoxy)-3,3,5-trimethylcyclohexane
Synonym 1,1-Bis(t-butylperoxy)-3,3,5-trimethylcyclohexane 1,1-Di-tert-butylperoxy-3,5,5-trimethylcyclohexane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} luperco231xlp {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} luperco231xl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} luperco231g
CAS Number6731-36-8
PubChem Substance ID93038
EC Number229-782-3
MDL NumberMFCD00084801
Chemical Name Translation1,1-双(叔丁基过氧基)-3,3,5-三甲基环己烷
InChIKeyNALFRYPTRXKZPN-UHFFFAOYSA-N
Beilstein Registry Number5932965
InChIInChI=1S/C17H34O4/c1-13-10-16(8,9)12-17(11-13,20-18-14(2,3)4)21-19-15(5,6)7/h13H,10-12H2,1-9H3
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分类

  • Free Radical Initiators, Materials Science, Organic Peroxides, Polymer Science, Polymerization Initiators
  • {SNA} Free Radical Initiators, Materials Science, Organic Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization

相关文献及参考

  • FT-IR 2 (1), 306:B / RegBook 1 (1), 211:E / Structure Index 1 , 29:B:5

安全信息

GHS Symbol
WGK Germany2
Hazard Codes O O,Xi
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H241 Heating may cause a fire or explosion 加热可能会引起火灾或爆炸
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSD8600000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P305+P351+P338
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P370+P378
  • P370+P380+P375
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P410+P412
  • P411 Store at temperatures not exceeding … oC/…oF. 储存在温度不超过…oC /…oF。
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
Risk Statements
  • R7 May cause fire 会导致起火
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R50 Very toxic to aquatic organisms 对水生生物极毒
UN Number UN 3110 5.2
Packing GroupⅠ
Hazard Class5.2
Storage condition +4°C Refrigerator (+4°C)
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 12918 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ESKHA5 Eisei Shikenjo Hokoku.  Bulletin of the Institute of Hygienic
   Sciences.  (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu,
   Setagaya-ku, Tokyo 158, Japan)  V.1-    1886-  Volume(issue)/page/year:
   (110),42,1992

其他信息

  • Sigma Aldrich:6731-36-8(sigmaaldrich)
  • Acros Organics:1,1-二叔丁过氧基-3，3，5-三甲基环己烷 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane, ,75% sol.in arom.free min.spirit(6731-36-8)
  • 用途一:用作聚乙烯、聚苯乙烯、乙烯-醋酸乙烯共聚物的交联剂，特别适用于收缩薄膜
  • MSDS 信息:Di-tert-butyl 3,3,5-trimethylcyclohexylidene diperoxide(6731-36-8).msds
  • 1,1-二叔丁基过氧化-3,3,5-三甲基环己烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 349772500 1,1-二叔丁基过氧化-3,3,5-三甲基环己烷 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane , 75% solution in aromatic free mineral spirit 250 ML 857元
  • MOL 文件:6731-36-8.mol

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Chromatography Reagents & Solvents - Analytical Reagents
  4. LC-NMR Solvents (CHROMASOLV®) - Chromatography Reagents & Solvents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Free Radical Initiators and Materials for Controlled Radical Polymerization
  5. Organic Peroxides - Free Radical Initiators

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