Methylphosphonic dichloride 二氯甲基膦
CAS 676-97-1 MFCD00002071
化学结构图
SMILES: CP(=O)(Cl)Cl
化学属性
| Mol. Formula | CH3Cl2OP |
|---|---|
| Mol. Weight | 132.91 |
| Boiling Point | 59-60°C/11mm |
| Vapor Pressure | 760 mmHg ( 163 °C) |
| Density | 1.468 |
| Melting Point | 28-34°C |
| Flash Point | >110°(230°F) |
| TSCA | Yes |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Methylphosphonic dichloride |
|---|---|
| Synonym | Methylphosphonyl dichloride (DC) 二氯甲基膦 Dichlormethylphosphinoxid methylphosphonyl chloride Methylphosphonoyldichlorid Methanphosphonsäuredichlorid methylphosphonodichloridic acid Dichloromethylphosphine oxide; Methanephosphonyl chloride; Methanephosphonyl dichloride; Methylphosphonic acid dichloride; Methanephosphonodichloridic acid Methyl phosphonic dichloride Methylphosphonyldichloride methylphosphonic acid dichloride methanephosphonyl chloride Methylphosphonyl dichloride Methylphosphonsäure-dichlorid methylphosphonic dichloride methanephosphonodichloridic acid Methylphosphonsäuredichlorid dichloromethylphosphine oxide Dichloromethylphosphine oxide Methanephosphonyl chloride Methylphosphonodichloridic acid Methylphosphonyl chloride Methylphosphonyl dichloride methyl-phosphonic acid-dichloride Methyl phosphonyl dichloride methylphosphonoyl dichloride Methanephosphonic dichloride Phosphonic dichloride, methyl- Methanephosphonyl dichloride Methylposphondichlorid Methyl-phosphoramide dichloride methyl-phosphonic acid dichloride |
| PubChem Substance ID | 12671 |
| EC Number | 211-634-4 |
| Beilstein Registry Number | 1071305 |
| MDL Number | MFCD00002071 |
| CAS Number | 676-97-1 |
| Chemical Name Translation | 二氯甲基膦 |
| InChIKey | SCLFRABIDYGTAZ-UHFFFAOYSA-N |
| Wiswesser Line Notation | OPGG1 |
| InChI | InChI=1S/CH3Cl2OP/c1-5(2,3)4/h1H3 |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
相关文献及参考
- Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts an
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H330 Fatal if inhaled 吸入致命
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P330+P331
- P302+P361+P354
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P308+P316
- P309+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P316
- P317
- P319
- P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R26 Very toxic by inhalation 吸入极毒
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 26 ppm/4H TOXIC EFFECTS : Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea Skin and Appendages - dermatitis, other (after systemic exposure) REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 25,470,1964
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