TEBBE Reagent Tebbe试剂
CAS 67719-69-1 MFCD00151575
化学结构图
SMILES: C[Al](C)C[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1
化学属性
| Mol. Formula | C13H18AlClTi |
|---|---|
| Mol. Weight | 284.58 |
| Density | 0.927 g/mL at 25 °C |
| Flash Point | 1°(34°F) |
| TSCA | No |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | TEBBE Reagent |
|---|---|
| Synonym | Tebbe Reagent TEBBE 试剂 溶液 双(环戊二烯基)-μ-氯化(二甲基铝)-μ-亚甲基钛 |
| MDL Number | MFCD00151575 |
| PubChem Substance ID | 24863730 |
| CAS Number | 67719-69-1 |
| Merck Number | 14,9091 |
| Chemical Name Translation | Tebbe试剂 |
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分类
- {SNA} 25mL Sure/Seal Reagents, C-C Bond Formation, Chemical Synthesis, Olefination, Organometallic Reagents, Others, Synthetic Reagents
- {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Others, Synthetic Reagents
- {SNA} 25mL Sure/Seal Reagents, C-C Bond Formation, Chemical Synthesis, Olefination, Organometallic Reagents, Other Olefination Reagents, Synthetic Reagents
相关文献及参考
- 1. Synthesis , 165, (1991)
- Bioorg. Med. Chem. 11 , 2489-2497, (2003) 摘要
- Org. Lett. 7 , 1645, (2005) 摘要
- Merck 14 ,9091
- Fieser 8 ,83 / Fieser 10 ,87 / Fieser 11 ,52 / Fieser 12 ,54 / Fieser 13 ,71 / Fieser 15 ,79 / Fieser 16 ,70 / Fieser 17 ,69
- Structure Index 1 , 494:B:5
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S30 Never add water to this product 切勿将水加入该产品中；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S8 Keep container dry 保持容器干燥；
- R11 Highly flammable 非常易燃
- R48/20
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R20 Harmful by inhalation 吸入有害
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