(E)-2-Phenylethenylboronic acid 反式-2-苯基乙烯基硼酸

CAS 6783-05-7 MFCD00963621

化学结构图

6783-05-7
SMILES: C=C(B(O)O)c1ccccc1

化学属性

Mol. FormulaC8H9BO2
Mol. Weight147.97
Melting Point146-156°C
TSCANo

别名和识别编码

Chemical Name(E)-2-Phenylethenylboronic acid
Synonym (E)-Styreneboronic acid {LY} (E)-Styreneboronic acid {} {LY} (E)-Styreneboronic acid {} {} {LY} (E)-Styreneboronic acid {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Styreneboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00963621
PubChem Substance ID5702628
CAS Number6783-05-7
Chemical Name Translation反式-2-苯基乙烯基硼酸
LabNetwork Molecule IDLN00216283
InChIInChI=1S/C8H9BO2/c10-9(11)7-6-8-4-2-1-3-5-8/h1-7,10-11H/b7-6+
Canonical SMILESOB(/C=C/C1=CC=CC=C1)O
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分类

  • {SNA} Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
  • Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • 1. Lu, G-P.; et al. , Ligand Effects on the Stereochemical Outcome of Suzuki-Miyaura Couplings J. Org. Chem. 8th ed., 77 , 370-3703, (2012)
  • 2. Nguyen, Q.; Sun, K.; Driver, T. G. , Rh2(II)-Catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source J. Am. Chem. Soc. 17th ed., 134 , 7262-7265, (2012) 摘要
  • 3. Wilson, J. E., Diastereoselective synthesis of tetrahydroquinolines via a palladium-catalyzed Heck-Suzuki cascade reaction Tetrahedron Lett. 18th ed., 53 , 2308-2311, (2012)
  • 4. Kim, J.; et al. , Copper-Mediated Sequential Cyanation of Aryl C-B and Arene C-H Bonds Using Ammonium Iodide and DMF J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012) 摘要
  • 5. Feng, X.; et al. , Rh(I)-Catalyzed Asymmetric 1,2-Addition to a-Diketones with Chiral Sulfur-Alkene Hybrid Ligands Org. Lett. 2nd ed., 14 , 624-627, (2012) 摘要
  • 6. Iwai, T.; et al. , Iridium-Catalyzed Addition of Aroyl Chlorides and Aliphatic Acid Chlorides to Terminal Alkynes J. Am. Chem. Soc. 2nd ed., 134 , 1268-1274, (2012) 摘要
  • 7. Greenaway, R. L.; et al. , alladium-Catalyzed Cascade Cyclization of Ynamides to Azabicycles Chem. Eur. J. 51th ed., 17 , 14366-14370, (2011)
  • 8. Li, Y.; Xu, M-H., Lewis acid promoted highly diastereoselective Petasis borono-Mannich reaction: Efficient synthesis of optically active β,γ-unsatd. α-amino acids Org. Lett. 8th ed., 14 , 2062-2065, (2012) 摘要
  • 9. Ascic, E.; et al. , Build/Couple/Pair Strategy Combining the Petasis 3-Component Reaction with Ru-Catalyzed Ring-Closing Metathesis and Isomerization ACS Comb. Sci. 4th ed., 14 , 253-257, (2012) 摘要
  • Chem. Commun. , 1200-1201, (2004)
  • J. Am. Chem. Soc. 129 , 1132, (2007) 摘要
  • Beil. 16 ,III,1279

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C {LY} -20°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

系列性分类


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