(S)-4-Hydroxypyrrolidin-2-One (S)-(-)-4-羟基-2-吡咯烷酮

CAS 68108-18-9 MFCD00273370

化学结构图

68108-18-9
SMILES: O[C@@H]1CNC(=O)C1

化学属性

Mol. FormulaC4H7NO2
Mol. Weight101.11
Melting Point156-159

别名和识别编码

Chemical Name(S)-4-Hydroxypyrrolidin-2-One
CAS Number68108-18-9
Alfabeta NameHYDROXYPYRROLIDINEONE S42()----
MDL NumberMFCD00273370
Synonym (4S)-4-Hydroxy-2-pyrrolidinone (S)-(-)-4-羟基-2-吡咯烷酮 (S)-4-Hydroxy-2-pyrrolidinone (S)-4-Hydroxy-2-pyrrolidone (S)-β-Hydroxy-γ-butyrolactam (S)-β-羟基-γ-丁内酰胺
PubChem Substance ID160871328
Beilstein Registry Number1524192
Chemical Name Translation(S)-(-)-4-羟基-2-吡咯烷酮
Reaxys-RN1524192
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines
  • Chiral Reagents
  • Heterocycles
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • Amines

产品应用

  • The (S)-enantiomer intermediate in the preparation of Oxiracetam

相关文献及参考

  • Kondepudi, D., et al.: Science, 250 975 (1990),
  • Di Silvestro, G., et al.: J. Pharm. Sci., 82, 758 (1993),
  • Beil. 21 ,V,12,18

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
Signal word Danger
Hazard Codes Xn
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Pyrrolidines - Heterocyclic Building Blocks

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