(1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene (1E,3Z)-1-甲氧基-2-甲基-3-(三甲基硅氧基)-1,3-戊二烯
CAS 72486-93-2 MFCD10567404
化学结构图
SMILES: C/C(=C\OC)/C(=C/C)/O[Si](C)(C)C
化学属性
| Mol. Formula | C10H20O2Si |
|---|---|
| Mol. Weight | 200.35 |
| Density | 0.899 g/mL at 25 °C(lit.) |
| Boiling Point | 65 °C/6 mmHg(lit.) |
| Refractive index | n20/D 1.4650(lit.) |
别名和识别编码
| Chemical Name | (1E,3Z)-1-Methoxy-2-methyl-3-(trimethylsilyloxy)-1,3-pentadiene |
|---|---|
| Synonym | (1E,3Z)-1-甲氧基-2-甲基-3-(三甲基硅氧基)-1,3-戊二烯 (1E,3Z)-1-甲氧基-2-甲基-3-[(三甲基硅烷基)氧]-戊-1,3-二烯 [(1-(2-甲氧基-1-甲基乙烯基)烯丙氧基]三甲基硅烷 (1E,3Z)-1-甲氧基-2-甲基-3-[(三甲基硅烷基)氧]-戊-1,3-二烯 [(1-(2-甲氧基-1-甲基乙烯基)烯丙氧基]三甲基硅烷 |
| MDL Number | MFCD10567404 |
| PubChem Substance ID | 24882659 |
| CAS Number | 72486-93-2 |
| Chemical Name Translation | (1E,3Z)-1-甲氧基-2-甲基-3-(三甲基硅氧基)-1,3-戊二烯 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- 1. Yu, Z.; et al., An N,N'-dioxide/In(OTf)3 catalyst for the asymmetric hetero-Diels-Alder reaction between Danishefsky's dienes and aldehydes: application in the total synthesis of triketide Angew. Chem. Int. Ed. Engl. 47 , 1308-1311, (2008)
- 2. Oskarsson, T.; et al., Diverted Total Synthesis Leads to the Generation of Promising Cell-Migration Inhibitors for Treatment of Tumor Metastasis: In vivo and Mechanistic Studies on the Migrastatin Core Ether Analog J. Am. Chem. Soc. 132 , 3224-3228, (2010)
- 3. Massa, A.; et al., A new approach to di- and tetrasubstituted 2,3-dihydropyridin-4(1H)-ones through aza-Diels-Alder reaction promoted by silicon tetrachloride Synthesis , 643-649, (2009)
- 4. Andreassen, T.; et al., The use of two optically active N-sulfinyl α-imino esters in the stereoselective aza-Diels-Alder reaction Tetrahedron 65 , 2806-2817, (2009)
安全信息
- H302 Harmful if swallowed 吞食有害
GHS Symbol
- R22 Harmful if swallowed 吞咽有害
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