Tetramethylammonium Iodide 四甲基碘化铵

CAS 75-58-1 MFCD00011629

化学结构图

75-58-1
SMILES: C[N+](C)(C)C.[I-]

化学属性

Mol. FormulaC4H12IN
Mol. Weight201.05
Density1.84
Melting Point>300°C
SolubilitySlightly soluble in water. Insoluble in chloroform, ether
TSCAYes
Stability对光和湿度敏感
Appearance 白色结晶至粉末状

别名和识别编码

Chemical NameTetramethylammonium Iodide
Synonym Tetramethylammonium (iodide) {LY} Tetramethylammonium (iodide) {} {LY} Tetramethylammonium (iodide) {} {} {LY} Tetramethylammonium (iodide) {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetramethylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {}
CAS Number75-58-1
EC Number200-881-3
Beilstein Registry Number3620030
MDL NumberMFCD00011629
PubChem Substance ID6381
Merck Number9225
Reaxys-RN3620030
Chemical Name Translation四甲基碘化铵
Wiswesser Line Notation1K1&1&1 &Q &I
LabNetwork Molecule IDLN00200450
InChIInChI=1S/C4H12N.HI/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
Canonical SMILESC[N+](C)(C)C.[I-]
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
  • {uni_hamburg} no charge; 2fragments; ionic

产品应用

  • 极谱分析,测定锗。芳香族化合物的简易碘化包括苯胺,酸,醇.

相关文献及参考

  • Short: II/27B
  • Short: III/31a
  • Short: III/10a
  • Merck: 14,9225
  • Merck: 14,9225 Beilstein:4,51

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
RTECSPA1050000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Packing GroupIII
UN Number UN2811
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} { {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xi
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 33 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 25,315,1925

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3560 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 4,381,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   UCPHAQ University of California, Berkeley, Publications in Pharmacology.
   (Berkeley, CA)  V.1-3, 1938-57.  Discontinued.  Volume(issue)/page/year:
   1,187,1939

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1800 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01073

其他信息

  • 用途一:极谱分析,测定锗。用作相转移催化剂。
  • Sigma Aldrich:75-58-1(sigmaaldrich)
  • 图谱信息:四甲基碘化铵(75-58-1)红外图谱(IR2) 四甲基碘化铵(75-58-1)红外图谱(IR1) 四甲基碘化铵(75-58-1)核磁图( 1 HNMR) 四甲基碘化铵(75-58-1)质谱(MS) 四甲基碘化铵(75-58-1)核磁图( 13 CNMR)
  • MSDS 信息:Tetramethylammonium iodide(75-58-1).msds
  • Acros Organics:四甲基碘化铵 Tetramethylammonium iodide, 99%(75-58-1)
  • F:8
  • 有吸湿性。约230℃开始分解。易溶于水,不溶于乙醇、乙醚和氯仿。半数致死量(小鼠,腹腔)40mg/kg。有刺激性。
  • 四甲基碘化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw060012 苄基三乙基溴化铵 500g 1800元 2011/08/23 xw060014 苄基三乙基溴化铵 100g 480元 2011/08/23 xw060020 苄基三乙基溴化铵 400g 1500元
  • 有吸湿性。约230℃开始分解。易溶于无水乙醇,微溶于水,不溶于乙醚和氯仿。半数致死量(小鼠,腹腔)40mg/kg。有刺激性。
  • TCI Shanghai:四甲基碘化铵 Tetramethylammonium Iodide,>;98.0%(T)(75-58-1)
  • MOL 文件:75-58-1.mol
  • 敏感性:Light Sensitive & Hygroscopic
  • Alfa Aesar:四甲基碘化铵,99% Tetramethylammonium iodide, 99%(75-58-1)

系列性分类


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