Trichlorovinylsilane 乙烯基三氯硅烷

CAS 75-94-5 MFCD00000482

化学结构图

75-94-5
SMILES: C=C[Si](Cl)(Cl)Cl

化学属性

Mol. FormulaC2H3Cl3Si
Mol. Weight161.49
Density1.27
Refractive index1.4340 to 1.4370
Flash Point18°C(lit.)
TSCAYes
Boiling Point90
Melting Point-95
Vapor Density>;1 (vs air)
Vapor Pressure60 mmHg ( 23 °C)
Solubility起反应

别名和识别编码

Chemical NameTrichlorovinylsilane
Synonym (TRICHLOROSILYL)ETHYLENE (Trichlorosilyl)ethylene, Vinyltrichlorosilane (十三氟-1,1,2,2-四氢辛基)-1-三氯硅烷 A 150 (silane) CV-4900 KA 1003 Silane, Vinyltrichloro- Silane, ethenyl tr Silane, trichlorovinyl- Silane, vinyl trichloro A-150 Silane,trichloroethenyl- TRICHLOROVINYLSILANE TSL 8303 Trichlor-vinylsilan Trichlorovinylsilane Trichlorovinylsilicon Trichlorvinylsilan Union carbide A-150 VTC VTCS Vinylsilicon trichloride Vinyltrichlorosilane; VTC a150(silane) silane, trichloroethenyl- silane,vinyltrichloroa-150 trichloro(vinyl)silane trichloro-vinyl-silane trichloroethenyl-silan
MDL NumberMFCD00000482
CAS Number75-94-5
EC Number200-917-8
Beilstein Registry Number1743440
PubChem Substance ID6413
Reaxys-RN1743440
Chemical Name Translation乙烯基三氯硅烷
Wiswesser Line NotationG-SI-GG1U1
LabNetwork Molecule IDLN00224520
InChIInChI=1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2
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分类

  • {SNA} Materials Science, Micro/NanoElectronics, Monomers, Nanomaterials, POSS Precursors and Intermediates, Polymer Science, RSiCl3, Self Assembly & Contact Printing, Self-Assembly Materials, Silane Coupling Agents/Adhesion Promo
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Micro/NanoElectronics, Monomers, Nanomaterials, POSS Precursors and Intermediates, Polymer Science, RSiCl3, Self Assembly and Lithography, Self-Assembly Materials, Silane Coupling Agents/Adhesion Promoters, Silanes, Silsesquioxanes: POSS Nanohybrids, Trichlorosilanes, Vinyl Halides, Amines, Amides, and Other Vinyl Monomers, 材料科学
  • {

相关文献及参考

  • Short: III/20a
  • Short: III/35F
  • Short: II/25B
  • Undergoes the ene (insertion) reaction with suitable alkenes: Compt. Rend., 278(C), 375 (1974).

安全信息

RTECSVV6125000
Packing GroupII
UN Number 1305
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S8 Keep container dry 保持容器干燥；
Storage condition Moisture Sensitive 0-6°C
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H311+H331
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes 3 F,C
Hazard Class3/8
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 680 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 1/19/1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1280 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

其他信息

  • 毒性分级:中毒
  • TCI Shanghai:乙烯基三氯硅烷 Trichlorovinylsilane,>;98.0%(GC)(75-94-5)
  • MSDS 信息:乙烯三氯硅烷(75-94-5).msds
  • 用途一:用于有机硅化合物的合成
  • Sigma Aldrich:75-94-5(sigmaaldrich)
  • 类别:易燃液体
  • 急性毒性:口服- 大鼠 LD50:1280 毫克/ 公斤; 吸入- 大鼠 LCL0: 500 PPM/ 4 小时
  • TSCA:Yes
  • 灭火剂:干粉、干砂、干石粉、二氧化碳
  • 乙烯基三氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0407 乙烯基三氯硅烷 Trichlorovinylsilane 500G 863元 2014/06/02 T0407 乙烯基三氯硅烷 Trichlorovinylsilane 25G 137元 2010/06/21 147425000 乙烯基三氯硅烷 Trichlorovinylsilane 96% 500 ML 1172元
  • 蒸气密度:>;1 (vs air)
  • MOL 文件:75-94-5.mol
  • 蒸气压:60 mm Hg ( 23 °C)
  • F:21
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 高热分解有毒光气; 遇水放出氯化物毒雾
  • 刺激数据:皮肤- 兔子 625 毫克 重度; 眼睛- 兔子 50 微克 重度
  • Acros Organics:乙烯基三氯硅烷 Trichlorovinylsilane, 96%(75-94-5)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • Alfa Aesar:三氯乙烯硅烷,97% Vinyltrichlorosilane, 97%(75-94-5)
  • 外观性质:无色液体。
  • 敏感性:Moisture Sensitive
  • 图谱信息:乙烯基三氯硅烷(75-94-5)红外图谱(IR1)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl - Halogenated Hydrocarbons
  1. Materials Science 材料科学
  2. Nanomaterials - Materials Science
  3. Silsesquioxanes: POSS® Nanohybrids - Nanomaterials
  4. POSS® Precursors and Intermediates - Silsesquioxanes: POSS® Nanohybrids
  5. RSiCl3 - POSS® Precursors and Intermediates
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Materials Science 材料科学
  2. Silane Coupling Agents 硅烷偶联剂

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