(S)-2,2’-Dimethoxy-1,1’-Binaphthalene (S)-2,2’-二甲氧基-1,1’-联萘

CAS 75640-87-8 MFCD00091146

化学结构图

75640-87-8
SMILES: COC1=CC=C2C=CC=CC2=C1C1C(=CC=C2C=CC=CC2=1)OC

化学属性

Mol. FormulaC22H18O2
Mol. Weight314.38
Melting Point227-231 °C (lit.)
TSCANo

别名和识别编码

Chemical Name(S)-2,2’-Dimethoxy-1,1’-Binaphthalene
Synonym (S)-1,1′-二-2-萘二甲醚 (S)-(-)-2,2′-Dimethoxy-1,1′-binaphthyl (R)-1,1′-二-2-萘二甲醚 (R)-(+)-2,2′-Dimethoxy-1,1′-binaphthyl (S)-(-)-2,2′-Dimethoxy-1,1′-binaphthyl (S)-(-)-2,2′-二甲氧基-1,1′-联萘 2,2′-二甲氧基-1,1′-联萘 (±)-1,1′-二-2-萘酚二甲醚 2,2′-Dimethoxy-1,1′-binaphthyl 2,2'-DIMETHOXY-1,1'-BINAPHTHYL (S)-1,1′-二-2-萘二甲醚 (R)-(+)-2,2′-二甲氧基-1,1′-联萘
MDL NumberMFCD00091146
PubChem Substance ID24881589
Beilstein Registry Number4704232
CAS Number75640-87-8
Chemical Name Translation(S)-2,2’-二甲氧基-1,1’-联萘
Reaxys-RN2060769
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分类

  • {SNA} Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Building Blocks, C22 to C40+, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • Asymmetric Synthesis, BINOLs, Building Blocks,

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Hazard Codes Xi,N Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
UN Number UN3077
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R50/53
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINOLs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINOLs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C22 to C40+ - Ethers

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