Chloropicrin 氯化苦

CAS 76-06-2 MFCD00041878

化学结构图

76-06-2
SMILES: O=[N+]([O-])C(Cl)(Cl)Cl

化学属性

Mol. FormulaCCl3NO2
Mol. Weight164.37
Refractive indexn20/D 1.461(lit.)
Density1.657 g/mL at 25 °C(lit.)
Boiling Point112 °C(lit.)
Solubility不溶于水，溶于乙醇、苯等多数有机溶剂。

别名和识别编码

Chemical NameMethane, trichloronitro-
Synonym Dolochlor KLOP Nemax chloropicrine(french) CHLOR-O-PIC(R) Tricloro-nitro-metano Tri-clor Picfume Trichlor-nitro-methan Methane, trichloronitro-, (absorbed) 氯化苦 Picride Chlorpicrin Trichloronitro-methane CCl3NO2 (trichloro-nitro-methane) chloropicrin,absorbed Dojyopicrin 硝基氯仿 Pic-Clor methane, trichloronitro- Profume A G 25 Trichloornitromethaan chloropicrinmixture,[withnocompressedgasorpoisonaliquid] Aquinite 硝氯仿 Chloorpikrine PS Chloropicrin Microlysin 硝基三氯甲烷 氯化苦; 三氯硝基甲烷; 硝基氯仿; 硝基三氯甲烷 CHLOROPICRIN TRICHLORONITROMETHANE NCI-C00533 chloropicrin,liquid(dot) nitrochloroform ACQUINITE(R) Nitrochloroform 三氯硝甲烷 Acquinite Nitrotrichloromethane Cloropicrina Chloropicrin mixture Trichlornitromethan Chloroform, nitro- 氯化苦劑 chloropicrin NEMAX(R) Chloropicrine Chlorpikrin Tri-Clor Larvacide Trichloronitromethane NITROCHLOROFORM(R) Nimax chloropicrinandnon-flammable,non-liquefiedcompressedgasmixture PICFUME(R) Chlor-o-pic 硝三氯甲烷 三氯硝基甲烷 LARVACIDE(R) trichloro-nitro-methane Chlor-o-pic nitr
MDL NumberMFCD00041878
PubChem Substance ID6423
Beilstein Registry Number1756135
EC Number200-930-9
CAS Number76-06-2
Chemical Name Translation氯化苦
Merck Number13,2175
Wiswesser Line NotationWNXGGG
InChIInChI=1S/CCl3NO2/c2-1(3,4)5(6)7
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SA} Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Fumigants, Fungicides, Insecticides, Nematicides, Others, Pesticides, Pesticides & Metabolites, Q-Z, T, TP - TZ
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, C, CH, Chromatography, Environmental Standards, Fumigants, Fungicides,

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.

安全信息

WGK Germany1
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H330 Fatal if inhaled 吸入致命
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSPB6300000
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
Hazard Codes T+
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R26 Very toxic by inhalation 吸入极毒
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 1580 UN 1580
Packing GroupI
Hazard Class6.1(a)
Storage condition 0-6°C
Restrict 剧毒化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 26 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-65,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 2000 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,169,1969

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 2 mg/m3
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   ZGEMAZ Zeitschrift fuer die Gesamte Experimentelle Medizin.  (Berlin, Fed.
   Rep. Ger.)  V.1-139, 1913-65.  For publisher information, see REXMAS.
   Volume(issue)/page/year: 106,296,1939

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 14400 ppb/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 16,63,1991

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 8 mg/L
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   10,21,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,185,1983

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 300 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 348,147,1995

Warnings 危险化学品

其他信息

  • 灭火剂:水、泡沫、砂土、二氧化碳
  • 急救治疗:[1]对症治疗。[2]禁忌用肾上腺素或阿托品。
  • 中毒症状:对人有强烈的催泪作用，为警戒性毒气，可致咳嗽，呕吐，半小时至1小时即有致命危险，对人吸入毒很高。
  • 类别:农药
  • 注意事项:种子胚部对氯化苦吸收力强，影响出芽率。
  • 可燃性危险特性:可燃; 遇酸分解有毒氮氧化物和氯化物气体
  • 外观性质:无色或微黄色油状液体，有催泪性。
  • 毒性分级:高毒
  • 急性毒性:口服- 大鼠 LD50: 250 毫克/ 公斤; 腹腔-小鼠LD50: 25 毫克/公斤
  • 用途一:氯化苦是一种有警戒性的薰蒸剂，可以杀虫、杀菌、杀鼠，也可用于粮食害虫薰蒸，还可用于木材防腐、房层、船舶消毒，土壤、植物种子消毒等。
  • 方法一:主要原料：三硝基苯酚，氢氧化钙、氯气。将石灰按一定比例加水，配制成石灰浆，然后将一定量石灰、三硝基苯酚、水混合制成钙盐送入氯化釜，加入石灰浆，在冷冻下，通氯氯化约2h，温度控制在32±1℃，然后又降温至7±1℃，氯化毕进行蒸馏而得。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、碱类分开存放
  • Sigma Aldrich:76-06-2(sigmaaldrich)
  • 职业标准:TWA 0.7 毫克/ 立方米; STEL 2 毫克/ 立方米
  • MSDS 信息:硝基三氯甲烷(76-06-2).msds
  • 上游原料:苦味酸
  • 爆炸物危险特性:加热， 摩擦可爆炸
  • MOL 文件:76-06-2.mol

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Insecticides - Pesticides
  8. Fumigants - Insecticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CH - C

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