Trimethyl(Phenyl)Silane 三甲基苯基硅烷

CAS 768-32-1 MFCD00008271

化学结构图

768-32-1
SMILES: C[Si](C)(C)c1ccccc1

化学属性

Mol. FormulaC9H14Si
Mol. Weight150.29
Density0.873
Refractive index1.4890 to 1.4920
Boiling Point168-170 °C at 760 mmHg
Flash Point44.4°C
TSCAYes
Stability对湿度敏感

别名和识别编码

Chemical NameTrimethyl(Phenyl)Silane
Synonym Phenyltrimethylsilane {LY} Phenyltrimethylsilane {} {LY} Phenyltrimethylsilane {} {} {LY} Phenyltrimethylsilane {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} { {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenyltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00008271
CAS Number768-32-1
EC Number212-192-5
Beilstein Registry Number16(4)1361
PubChem Substance ID87575393
Reaxys-RN1855012
Chemical Name Translation三甲基苯基硅烷
LabNetwork Molecule IDLN00203049
Canonical SMILESC[Si](C)(C)C1=CC=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others

相关文献及参考

  • Short: III/35D2
  • Reagent, in combination with iodine, for cleavage of esters and ethers, cf Iodotrimethyl­silane, A12902. Reported to be superior to TMS iodide for the cleavage of aryl ethers: Synthesis, 417 (1977).
  • Short: II/2
  • Beilstein:16(4)1361

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P403+P235
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P303+P361+P353
  • P305+P351+P338+P337+P313
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Hazard Codes Xi
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • 图谱信息:三甲基苯硅烷(768-32-1)质谱(MS) 三甲基苯硅烷(768-32-1)核磁图( 13 CNMR) 三甲基苯硅烷(768-32-1)红外图谱(IR1) 三甲基苯硅烷(768-32-1)核磁图( 1 HNMR)
  • TCI Shanghai:三甲基苯基硅烷 Trimethylphenylsilane,>;96.0%(GC)(768-32-1)
  • MOL 文件:768-32-1.mol
  • 三甲基苯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1299 三甲基苯基硅烷 Trimethylphenylsilane 25ML 442元 2010/05/25 L02876 苯基三甲基硅烷, 99% Phenyltrimethylsilane, 99% 5g 246元 2010/05/25 L02876 苯基三甲基硅烷, 99% Phenyltrimethylsilane, 99% 25g 832元
  • Alfa Aesar:苯基三甲基硅烷,99% Phenyltrimethylsilane, 99%(768-32-1)
  • Sigma Aldrich:768-32-1(sigmaaldrich)
  • Acros Organics:三甲基苯硅烷 Phenyltrimethylsilane, 99%(768-32-1)
  • 下游产品:三甲基溴硅烷
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Trialkoxysilanes - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Siloxanes 硅氧烷
  1. Materials Science 材料科学
  2. Silane Coupling Agents 硅烷偶联剂

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