(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one (3R,4R)-4-乙酰氧基-3-[(R)-叔丁基二甲硅氧基)乙基]-2-氮杂环丁酮

CAS 76855-69-1 MFCD00077636

化学结构图

76855-69-1
SMILES: CC(=O)O[C@H]1NC(=O)[C@H]1[C@@H](C)O[Si](C)(C)C(C)(C)C

化学属性

Mol. FormulaC13H25NO4Si
Mol. Weight287
Melting Point107-109
Density1.422

别名和识别编码

Chemical Name(3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one
MDL NumberMFCD00077636
PubChem Substance ID87562608
CAS Number76855-69-1
EC Number408-050-9
Reaxys-RN4690202
Beilstein Registry Number2384789
Synonym [3R(1′R,4R)]-(+)-4-乙酰氧基-3-[1-(叔丁基二甲基硅氧基)乙基]-2-氮杂环丁酮
Chemical Name Translation(3R,4R)-4-乙酰氧基-3-[(R)-叔丁基二甲硅氧基)乙基]-2-氮杂环丁酮
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks

相关文献及参考

  • FT-NMR 1 (3), 694:B / RegBook 1 (2), 2989:I / Structure Index 1 , 473:E:6

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P305+P351+P338+P337+P313
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P302+P352+P333+P313+P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P333+P313
  • P302+P350
  • P337+P313
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Signal word
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
UN Number
Safety Statements
Risk Statements
Packing GroupIII
Hazard Class9

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Lactams - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Lactams - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 4-Membered Ring Compounds

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