Triethyl 2-acetoxypropane-1,2,3-tricarboxylate 2-乙酰柠檬酸三乙酯

CAS 77-89-4 MFCD00049378

化学结构图

77-89-4
SMILES: CCOC(=O)CC(CC(=O)OCC)(OC(C)=O)C(=O)OCC

化学属性

Mol. FormulaC14H22O8
Mol. Weight318.32
Density1.136 g/mL at 25 °C(lit.)
Boiling Point228-229 °C at 100 mmHg
Refractive index1.4370 to 1.4400
Flash Point188°C(lit.)
Appearance 无色透明油状液体，沸点132℃（133.3Pa），闪点（开杯）188℃，在矿物油中的溶解度为1.2%（体积），与醋酸纤维素、硝酸纤维素、醋酸丁酸纤维素、乙基纤维素相容。本品沸点高、挥发性小、耐水解，可使油漆获得较好的耐光性。无毒，LD50=1150mg/kg体重。
Melting Point-42 °C
Stability易吸湿

别名和识别编码

Chemical NameTriethyl 2-acetoxypropane-1,2,3-tricarboxylate
Synonym Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {} {} {} {} {} {LY} Triethyl 2-acetoxypropane-1,2,3-tricarboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00049378
CAS Number77-89-4
Beilstein Registry Number1804947
EC Number201-066-5
PubChem Substance ID6504
Reaxys-RN1804947
Chemical Name Translation2-乙酰柠檬酸三乙酯
Wiswesser Line Notation2OV1XVO2&OV1&1VO2
LabNetwork Molecule IDLN00198639
InChIInChI=1S/C14H22O8/c1-5-19-11(16)8-14(22-10(4)15,13(18)21-7-3)9-12(17)20-6-2/h5-9H2,1-4H3
Canonical SMILESO=C(CC(C(OCC)=O)(OC(C)=O)CC(OCC)=O)OCC
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SA} Building Blocks, C12 to C63, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

安全信息

RTECSGE8225000
WGK Germany1
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 8510 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   1,283,1959

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1150 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Vascular - other changes
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 53,774,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 7 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P333+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 急性毒性:口服-大鼠 LD50:7000 毫克/公斤; 腹腔-小鼠 LD50: 1150 毫克/公斤
  • 可燃性危险特性:可燃; 加热分解释放刺激烟雾
  • 储运特性:库房通风低温干燥
  • 用途一:用作塑料的增塑剂
  • MOL 文件:77-89-4.mol
  • 毒性分级:中毒
  • 图谱信息:乙酰柠檬酸三乙酯(77-89-4)红外图谱(IR1) 乙酰柠檬酸三乙酯(77-89-4)Raman光谱
  • MSDS 信息:2-(Acetyloxy)-1,2,3-propanetricarboxylic acid triethyl ester(77-89-4).msds
  • TCI Shanghai:O-乙酰柠檬酸三乙酯 O-Acetylcitric Acid Triethyl Ester,>;97.0%(GC)(77-89-4)
  • Sigma Aldrich:77-89-4(sigmaaldrich)
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 乙酰柠檬酸三乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0086 O-乙酰柠檬酸三乙酯 Triethyl O-Acetylcitrate 500G 407元 2014/06/02 A0086 O-乙酰柠檬酸三乙酯 Triethyl O-Acetylcitrate 25G 163元
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Application Areas 应用领域分类
  2. Detergents 去污剂洗净剂
  3. Anionic Detergents - Detergents
  1. Application Areas 应用领域分类
  2. Detergents 去污剂洗净剂
  3. Non-Ionic Detergents - Detergents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrroles 吡咯
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C12 to C63 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C12 to C63 - Esters
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Pharmaceutical Standards - Chromatography
  5. Pharmaceutical Secondary Standards - Pharmaceutical Standards
  1. Materials Science 材料科学
  2. Plasticizer

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