Nitrogen trifluoride 三氟化氮

CAS 7783-54-2 MFCD00042549

化学结构图

7783-54-2
SMILES: FN(F)F

化学属性

Mol. FormulaF3N
Mol. Weight71.01
Melting Point-207 ºC
Boiling Point-129 ºC
Solubility不溶

别名和识别编码

Chemical NameNitrogen trifluoride
Synonym Fluorstickstoff N,N,N-Trifluoroamine NF(3) gas NF3 NITROGEN TRIFLUORIDE NITROGEN TRIFLUORIDE: 99.99% Nitrogen fluoride Nitrogen fluoride (NF3) Nitrogen trifluoride Nitrogen trifluoride 99% Nitrogentrifluoride99% Perfluoroammonia Stickstoff(III)-fluorid Stickstofftrifluorid Trifluoramine Trifluoroamine Trifluoroammonia nitrogen fluoride nitrogen trifluoride nitrogenfluoride(nf3) perfluoroammonia trifluoroamine trifluoroammonia 三氟化氮 氟化氮
MDL NumberMFCD00042549
CAS Number7783-54-2
EC Number232-007-1
Chemical Name Translation三氟化氮
Wiswesser Line NotationN F3
PubChem Substance ID24553
InChIInChI=1S/F3N/c1-4(2)3
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分类

  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster; Physi

安全信息

UN Number 2451
Hazard Codes O
Hazard Class2.2
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S17 Keep away from combustible material 远离可燃物料;
  • S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
Risk Statements
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
  • R20 Harmful by inhalation 吸入有害
Warnings 危化品目录(2015) 危险化学品
RTECSQX1925000
{

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Primate - monkey
DOSE/DURATION           : 7500 ppm/1H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-69-84,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Primate - monkey
DOSE/DURATION           : 7500 ppm/1H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 9600 ppm/1H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-69-84,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6700 ppm/1H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - cyanosis
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc.,

Hazard statements
  • H270 May cause or intensify fire; oxidizer 可能导致或加剧燃烧;氧化剂。
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
  • H332 Harmful if inhaled 吸入有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Precautionary statements
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P244 Keep reduction valves free from grease and oil.? 保持减压阀无油,无油脂。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P304+P312
  • P304+P340
  • P309+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P370+P376
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P405 Store locked up. 上锁保管。
  • P410+P403
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 可燃性危险特性:遇氢气、油脂助燃; 受热分解有毒氟化物和氮氧化物气体
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与氢气、还原剂、油脂分开存放
  • MOL 文件:7783-54-2.mol
  • 毒性分级:中毒
  • 外观性质:无色、带霉味的气体。
  • Hazard Note:Strong oxidising agent
  • 灭火剂:雾状水、泡沫
  • MSDS 信息:三氟化氮(7783-54-2).msds
  • 急性毒性:吸入- 大鼠 LC50: 6700 PPM/ 1 小时; 吸入- 小鼠 LC50: 2000 PPM/4小时
  • 类别:有害气体
  • 职业标准:TWA 29 毫克/ 立方米; STEL 29 毫克/ 立方米

系列性分类


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