Iodine Monobromide 一溴化碘

CAS 7789-33-5 MFCD00011353

化学结构图

7789-33-5
SMILES: BrI

化学属性

Mol. FormulaI Br
Mol. Weight206.81
Density4.41
Flash PointNone
TSCAYes
Boiling Point
Melting PointNo Data Available
Stability对光和潮气和空气敏感
Solubility溶于水。

别名和识别编码

Chemical NameIodine Monobromide
MDL NumberMFCD00011353
Synonym BROMINE IODIDE Bromine iodide Bromoiodine HANUS SOL FOR THE DET. OF IODINE VALUE IBr IODINE 0,1 MOL IBR/L, VOLUMETRIC SOLUTIO N ACCORDING TO HANUS IODINE BROMIDE Iodine Monobromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number232-159-9
CAS Number7789-33-5
Merck Number14,5016
Beilstein Registry Number3902973
PubChem Substance ID82238
Chemical Name Translation一溴化碘
LabNetwork Molecule IDLN02127159
InChIInChI=1S/BrI/c1-2
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, C-X Bond Formation (Halogen), Chemical Synthesis, G - M, Halogenated Solutions, Iodine and Iodide solutions, Most common compounds for volumetric titration, Others, Salt Solutions, Synthetic Reagents, Titration,
  • {SNA} C-X Bond Formation (Halogen),

相关文献及参考

  • Reagent for mild, selective deprotection of TBDMS ethers in carbohydrates and nucleosides: Synlett, 311 (1999).
  • Merck: 14,5016
  • Also found to give higher diastereoselectivity than iodine in the cyclization of certain homoallylic carbonates: Tetrahedron Lett., 33, 6439 (1992).
  • Selective brominating agent, considered to be intermediate in electrophilic power between bromine and iodine: J. Chem. Soc., 1509 (1939); J. Am. Chem. Soc., 60, 256 (1938); Chem. Commun., 849 (1968).
  • Short: II/24A

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
UN Number 3260 UN3260
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Storage condition -20 -20°C -20℃ Moisture & Light Sensitive Refrigerator (+4°C) 储存温度2-8℃ 对光敏感,避光保存。
Hazard Codes 8 C
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Packing GroupII
Hazard Class8
Warnings 危化品目录(2015) 危险化学品

其他信息

  • 用途一:用于有机合成
  • MSDS 信息:溴化碘(7789-33-5).msds
  • MOL 文件:7789-33-5.mol
  • F:1-8
  • Sigma Aldrich:7789-33-5(sigmaaldrich)
  • 溶于水,溶于乙醇、乙醚、二硫化碳和冰醋酸。
  • 敏感性:Moisture & Light Sensitive
  • 一溴化碘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A22484701 一溴化碘 50g 727元 2010/06/21 208842500 一溴化碘 Iodine monobromide 98% 250 GR 2533元 2010/06/21 208840500 一溴化碘 Iodine monobromide 98% 50 GR 695元
  • 外观性质:黑褐色晶体。
  • Acros Organics:一溴化碘 Iodine monobromide, 98%(7789-33-5)
  • Alfa Aesar:单溴化碘,99%min Iodine monobromide, 98% min(7789-33-5)

系列性分类


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