Chlorosulfonic acid 氯磺酸

CAS 7790-94-5 MFCD00011523

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H34321
Chlorosulfonic acid 氯磺酸
99%, SpcSeal 25g ¥ 80
库存 辽宁
中国国内现货 96-99 %
INFI H34321
Chlorosulfonic acid 氯磺酸
99%, SpcSeal 100g ¥ 100
96-99 %
INFI H34321
Chlorosulfonic acid 氯磺酸
99%, SpcSeal 500g ¥ 300
96-99 %
INFI H12933
Chlorosulfonic acid 氯磺酸
91%, SpcSeal 25g ¥ 50
库存 辽宁
中国国内现货 90+ %
INFI H12933
Chlorosulfonic acid 氯磺酸
91%, SpcSeal 100g ¥ 80
90+ %
INFI H12933
Chlorosulfonic acid 氯磺酸
91%, SpcSeal 500g ¥ 221
90+ %
Innochem I01596
≧99% 2.5L ¥ -
Innochem I03653
99% 100g ¥ -
96-99 %
Innochem I03653
99% 500g ¥ -
96-99 %
Innochem I03699
98%+ 500g ¥ -
96-99 %
Innochem I04741
Chlorosulfonic acid 氯磺酸
99.5% 2.5L ¥ -
99e1 %
Alfa 087977
Chlorosulfonic acid
typically 99% 250g ¥ 394
96-99%
Alfa 087977
Chlorosulfonic acid
typically 99% 1kg ¥ 1,577
96-99%
TCI C1788
97.0%(T) 500g ¥ 290
96-99%
J&K 320534
Chlorosulfonic acid, 99%
99% 500g ¥ 276
库存 HB SH
中国国内现货 96-99 %
J&K 320534
Chlorosulfonic acid, 99%
99% 1L ¥ 496
96-99 %
Acros 30449
Chlorosulfonic acid, 97%
100mL ¥ 140
96-99%
Acros 30449
Chlorosulfonic acid, 97%
500mL ¥ 451
96-99%
Acros 30449
Chlorosulfonic acid, 97%
1L ¥ 681
96-99%
Acros 30449
Chlorosulfonic acid, 97%
2.5L ¥ 1,586
96-99%
TRC TRC-C382800
Chlorosulfonic Acid
25g ¥ 1,320
TRC TRC-C382800
Chlorosulfonic Acid
50g ¥ 1,500
TRC TRC-C382800
Chlorosulfonic Acid
250g ¥ 2,100
TRC TRC-C382800
Chlorosulfonic Acid
500g ¥ 2,700
TRC C382800
25g ¥ 3,540
TRC C382800
50g ¥ 3,750
TRC C382800
250g ¥ 4,450
TRC C382800
500g ¥ 5,150
Energy-chemical W830201
Chlorosulfonic acid 氯磺酸
500g ¥ 362
库存 上海市
中国国内现货
Energy-chemical W830201
Chlorosulfonic acid 氯磺酸
750g ¥ 500
库存 上海市
中国国内现货
3A A01592
Chlorosulfonic acid 氯磺酸
99%,SpcSeal 100g ¥ 130
96-99 %
3A A01592
Chlorosulfonic acid 氯磺酸
99%,SpcSeal 500g ¥ 380
96-99 %
Acros 304490025
97% 2.5L ¥ 1,947
96-99 %
Acros 304491000
97% 100mL ¥ 261
96-99 %
Acros 304495000
97% 500mL ¥ 559
96-99 %
Acros 304490010
97% 1L ¥ 845
96-99 %

分类

  • Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents TLC, Glycosides, Inorganic Acids, Steroids, Terpenes, Lipids, Bile acids, Synthetic Reagents, TLC Reagents, A-C, TLC Visualization Reagents (alphabetic sort), TLC Visualization Reagents (by application)
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents TLC, Glycosides, Inorganic Acids, Steroids, Terpenes, Lipids, Bile acids, Synthetic Reagents, TLC Reagents, A-C, TLC Visualization Reagents (alphabeti

相关文献及参考

  • Merck 14 ,2165
  • Fieser 1 ,140 / Fieser 2 ,70 / Fieser 6 ,121
  • Aldrich MSDS 1 , 458:A / Corp MSDS 1 (1), 858:A / IR-Spectra (3), 542:A / IR-Spectra (2), 479:F / RegBook 1 (3), 3251:E / Sax 6 , 775
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany1
Hazard Codes
  • 8
  • C
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment
  • Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSFX5730000
Precautionary statements
  • P280301+330+331303+361+353305+351+338304+340310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 如接触到眼睛:小心地用水冲洗几分钟。如果佩戴隐形眼镜并容易取出的话,取出隐形眼镜。继续冲洗。
Signal word
Packing GroupI
UN Number
  • UN 1754 8/PG 1
  • UN1754
Risk Statements
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R35 Causes severe burns 会导致严重灼伤
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Storage condition
  • Moisture Sensitive
Hazard Class8
Warnings
  • 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - cyanosis
   Skin and Appendages - hair
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0570953

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 926 mg/m3/1H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - structural or functional change in trachea
   or bronchi
   Liver - changes in liver weight
   Blood - changes in spleen
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0570953

其他信息

  • 所属类别二:农药中间体: 杀螨剂中间体
  • 参考质量标准:国家标准GB 13549—92 指标名称 指标 优等品 一等品 合格品 外观 无色或黄色液体应无明显浑浊 淡棕色液体允许有点浑浊 棕色液体允许有浑浊 氯磺酸(HSO3C1)/%≥ 98.0 97.0 95.0 硫酸(H2SO4)/%\≤ 2.0 2.5 4.0 灰分/%≤ 0.03 不规定 不规定 铁/%≤ 0.01 0.01 不规定 铜/%≤ 0.003 0.003 不规定 色度/ml≤ 10 不规定 不规定
  • {Che
  • 防护措施:其蒸气对眼睛和粘膜有刺激作用。如吸入,应立即给氧,并送医院治疗;如不慎溅入眼睛时应立即用水冲洗15min,并送医院治疗;如与皮肤接触,能引起严重的灼伤,必须迅速用冷水冲洗,然后涂以3%碳酸氢钠溶液或药用獾油。 操作人员工作时应穿防酸织物工作服,戴防护眼镜、乳脱手套、胶皮围裙,空长筒胶靴等。生产设备要密闭、车间通风应良好。要进行就业前和每二年一次的定期体检。
  • {Chem
  • 用途三:氯磺酸用于合成杀螨剂三氯杀螨砜的中间体2,4,5-三氯苯磺酰氯,并用于合成糖精和磺胺药品,也用于制造洗涤剂、离子交换树脂、塑料、染料中间体的磺化剂等,军事上用作烟幕剂。
  • 毒性分级:高毒
  • 方法三:氯磺酸在制备上分为气相和液相两种方法:1.气相法:将三氧化硫和氯化氢两种气体导入反应器內起化合作用,经过冷卻后即凝结为氯磺酸,这种方法适宜于大量制备,因设备需要特种材料,投资较大。2.液相法:利用粗制氯磺酸或浓硫酸作母液,先将三氧化硫通入母液內吸收,然后再通以氯化氢,使两种气体在液相內起化学作用,生成氯磺酸。此法可以进行小規模制备
  • 下游产品:2-噻吩磺酰氯 --> 月桂醇聚氧乙烯醚硫酸酯钠盐 --> 4-氯苯磺酰胺 --> α-乙酰氨基对甲苯磺酰氯 --> 三氯杀螨砜 --> 2-[(4-氨基苯基)磺酰基]乙醇硫酸氢酯 --> 5-氯-4-硝基噻酚-2-磺酰氯 --> 3-(4-磺酰氯)苯丙酸甲酯 --> 2,5-二氯噻吩-3-磺酰胺 --> 对联苯磺酰氯 --> 2,4-二氯苯磺酰氯 --> 2,4,6-三氟苯磺酰氯 --> 2,4,5,6-四甲基苯二磺酸氯 --> 2,4-二氯-5-磺酰胺基苯甲酸 --> 分散黄M-FL --> 2-氨基-4-氯嘧啶 --> 2,4-二磺酰氯基均三甲苯 --> 1,3-苯并二氧-5-磺酰氯 --> 5-氯噻唑-2-磺酰氯 --> 溶蒽素蓝IBC --> 环拉酸 --> 2,3,4,5-四氯硝基苯 --> 对氯苯基对氯苯磺酸酯 --> 磺胺灭脓 --> 3,5-二甲基异唑-4-磺酰氯 --> 2-(氯甲基)-1-甲基-4-硝基苯 --> 苯磺酸甲酯 --> 4-乙酰氨基甲基苯磺酰胺 --> 三甲基铵三氧化硫共聚物 --> 4,5-二溴噻吩-2-磺酰氯 --> 杀螨砜 --> 硫化绿14 --> N,N-二甲基-N-十六酰胺基丙基季铵基乙硫酸酯 --> 氯磺酸乙酯
  • 用途五:制造磺胺药物、活性染料、洗涤剂、塑料、农药、糖精及国防工业原料等。
  • MSDS 信息:氯磺酸(7790-94-5).msds
  • 氯磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80035627 氯磺酸(*)(剧毒) 250ml 290元 2010/06/21 304491000 氯磺酸 Chlorosulfonic acid 97% 100 ML 654元 2010/06/21 304495000 氯磺酸 Chlorosulfonic acid 97% 500 ML 787元
  • 灭火剂:砂土、二氧化碳。禁止用水
  • 储运特性:库房通风低温干燥; 与H发孔剂、氰化物分开存放
  • 类别:腐蚀物品
  • 毒性:其蒸气对眼睛和黏膜有刺激作用。如吸入,应立即给氧,并送医院治疗;如不慎溅入眼睛时应立即用水冲洗15 rain,并送医院治疗;如与皮肤接触,能引起严重的灼伤,必须迅速用冷水冲洗,然后涂以3%碳酸氢钠溶液或药用獾油。 操作人员工作时应穿防酸织物工作服,戴防护眼镜、乳胶手套、胶皮围裙,穿长筒胶靴等。生产设备要密闭、车间通风应良好。要进行就业前和每二年一次的定期体检。
  • 蒸气压:1 mm Hg (

化学结构图

CAS 7790-94-5  MFCD00011523
SMILES: O=S(=O)(O)Cl

化学属性

Mol. FormulaHClO3S
Mol. Weight116.52
Refractive index1.4331
Boiling Point155
Density1.753
Vapor Density4 (vs air)
Vapor Pressure1 mmHg ( 25 °C)
TSCAYes
Melting Point-80
Solubility起反应
Flash Point158°C

别名和识别编码

Chemical NameChlorosulfonic acid
CAS Number7790-94-5
PubChem Substance ID24638
EC Number232-234-6
MDL NumberMFCD00011523
Synonym
  • AKOS BBS-00004309
  • Monochlorosulfuric acid
  • CHLOROSULFONIC ACID, 99% (POLY-COATED BOTTLES)
  • Chlorosulfonic acid
  • CHLOROSULFONIC ACID, 99% (MINI-BULK)
  • CHLOROSULFONIC ACID REAGENT GRADE >=9&
  • CHLOROSULFURIC ACID
  • chlorosulfonic acid
  • Chlorosulfonicacid,typically99%
  • 氯磺酸, 一般为99%
  • Sulfuric chlorohydrin
  • SULFURIC CHLOROHYDRIN
  • Sulfonic acid, monochloride
  • Chlorsulfonsure
  • 氯硫酸
  • sulfuric acid chlorohydrin
  • 氯化硫酸
  • CHLOROSULFONIC ACID
  • Chloroschwefelsäure
  • CHLOROSULFONIC ACID 99%
  • CHLOROSULFONICACID,REAGENT
  • chlorosulphonic acid
  • CHLOROSULFONICACID,97%
  • Chlorschwefelsäure
  • monochlorosulfuric acid
  • acidechlorosulfonique
  • Chlorsulfonsäure
  • Chlorosulfonic acid, typically 99%
  • chlorosulfonic
  • 氯磺酸
  • sulfonicacid,monochloride
  • Monochlorosulfonic acid
  • monochlorosulfuricacid
  • chlorosulphuric acid
  • Sulfuric chlorohydrine
    Merck Number14,2165
    Chemical Name Translation氯磺酸
    Wiswesser Line NotationQSGO&O
    LabNetwork Molecule IDLN00195278
    Reaxys-RN1098595
    InChIInChI=1S/ClHO3S/c1-5(2,3)4/h(H,2,3,4)

    系列性分类


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