Phosphorodithioic acid,S-((4,6-diamino-s-triazin-2-yl)methyl) O,O-dimethylester 灭蚜松

CAS 78-57-9 MFCD00213927

化学结构图

78-57-9
SMILES: COP(=S)(OC)SCc1nc(N)nc(N)n1

化学属性

Mol. FormulaC6H12N5O2PS2
Mol. Weight281.32
Solubility微溶于水，溶于乙二醇、2-甲氧基乙醇、四氢糖醇、四氢呋喃。

别名和识别编码

Chemical NamePhosphorodithioic acid,S-((4,6-diamino-s-triazin-2-yl)methyl) O,O-dimethylester
Chemical Name Translation灭蚜松
Synonym (3-特丁基-1-二甲基氨基甲酰-1H-1,2,4-三唑-5-基硫)乙酸乙酯 1-二甲胺基甲酰基-3-特丁基-5-羰乙氧甲硫基-1,2,4-三唑 2,4-Diamino-6- 2,4-diamino-6-dimethoxyphosphinothionylthiomethyl-s-triazine 4,6-diamino-1,3,5-triazin-2-ylmethylo,o-dimethylphosphorodithioate AZIDITHION Azidit Azidithion {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number78-57-9
Wiswesser Line NotationT6N CN ENJ BZ DZ F1SPS&O1&O1
Beilstein Registry Number0668792
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安全信息

Hazard Codes Xn
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R52/53
  • R22 Harmful if swallowed 吞咽有害
RTECSTD5600000 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 890 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARSIM* Agricultural Research Service, USDA Information Memorandum.
   (Beltsville, MD 20705)  Volume(issue)/page/year: 20,14,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag
   New York, Inc., 1971  Volume(issue)/page/year: -,373,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >800 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SPEADM Special Publication of the Entomological Society of America.  (4603
   Calvert Rd., College Park, MD 20740)  Volume(issue)/page/year: 78-1,48,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - chicken
DOSE/DURATION           : 487 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   7,606,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2 gm/kg
TOXIC

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 5 ppm
REFERENCE :
   RSTUDV Rivista di Scienza e Technologia degli Alimenti e di Nutrizione
   Umana.  Review of Science and Technology of Food and Human Nutrition.
   (Bologna, Italy)  V.5-6, 1975-76.  Discontinued.  Volume(issue)/page/year:
   6,161,1976

其他信息

  • 外观性质:无色结晶。
  • MOL 文件:78-57-9.mol
  • 用途:氨基甲酸酯类内吸性杀虫剂，胆碱酯酶抑制剂。分子结构中含三唑基团，是广谱、高效、高选择性的杀蚜药剂，对抗性蚜虫也有良好的防效。由于该药剂能在作物脉管中形成上、下双相传导，因此土壤用药可防治食叶性蚜虫，而叶面喷施可防治食根性蚜虫，从而保护整个植株。推荐用药量为0.6～0.9g有效成分/100m 2 ，防治抗性蚜虫及棉蚜需0.9～1.5/100m 2 ，防治伏蚜需1.8～2.3g/100m 2 。药剂持效期长达10～15d。
  • 生产方法:3-特丁基-5-巯基-1，2，4-三唑的制备 2，2-二甲基丙酰氯与氨基硫脲作用，生成酰化氨基硫脲，再用氢氧化钠水溶液处理，环合生成3-特丁基-5-巯基-1，2，4-三唑。 唑蚜威的合成 3-特丁基-5-巯基-1，2，4-三唑与氯乙酸乙酯反应后，再与二甲基氨基甲酰氯反应合成唑蚜威。

系列性分类

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