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• Analytical Standards, Analytical/Chromatography, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromatography, Electronic Chemicals, Environmental Standards, Fumigants, Gases, Insecticides, Materials Science, Micro/NanoElectronics, Pesticides, Pesticides & Metabolites, Phosphine Compounds, Phosphorus Precursors, Specialty Gases, Synthetic Reagents, Vapor Deposition Precursors
• {uni_hamburg} no charge; 1fragment
• {SNA} Analytical Standards, Analytical/Chromatography, CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry,
• {SNA} Analytical Standards,

相关文献及参考

• Merck 14 ,7338
• Fieser 1 ,859 / Fieser 2 ,329
• Sax 6 , 2211 / Vapor Phase 3 , 837:A
• Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
• Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.

安全信息

GHS Symbol

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - cat
DOSE/DURATION           : 70 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,75,1982

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 140 mg/m3/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,75,1982

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2500 ppm/20M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie.  (Leipzig,
   Ger. Dem. Rep.)  V.1-109, 1873-1925.  For publisher information, see NSAPCC.
    Volume(issue)/page/year: 27,314,1890

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   36,452,1975

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 1400 ng/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   246,251,1989

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 5 ppm/6H/13W (Intermittent)
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   24,81,1994

其他信息

• 上游原料:亚磷酸 --> 3-氨基-4-氯苯磺酸
• 毒性分级:剧毒
• 爆炸物危险特性:与空气混合明火、受热可爆
• MSDS 信息:磷化氢(7803-51-2).msds
• 蒸气密度:1.15 (vs air)
• 类别:有害气体
• 外观性质:无色，有类似大蒜气味的气体。
• 急性毒性:吸入-大鼠 LC50: 11 PPM/4小时; 吸入-小鼠 LCL0:380 毫克/立方米/2小时
• 储运特性:库房通风低温干燥; 轻装轻卸; 与氧气、空气等助燃气体钢瓶分开存放
• 用途一:用于集成电路制造
• MOL 文件:7803-51-2.mol
• 可燃性危险特性:明火、受热可燃; 燃烧产生有毒磷氧化物烟雾
• 灭火剂:雾状水、二氧化碳、泡沫
• 下游产品:丁醛 --> 丙醛 --> 地虫磷 --> 荧光增白剂 CBS,荧光增白剂 BLS-X,4,4'-双-(2-二磺酸钠苯乙烯基)-联苯 --> 贝前列素 --> 氧化镧 --> 磷亚威 --> 4,4'-双[2-(邻氰苯基)乙烯基]苯 --> 2-(噻吩甲基)膦酸二乙酯 --> 2-(7-氯-1,8-二氮萘-2-基)-3-[2-(1,4-二氧-8-氮杂螺[4.5]庚-8-基)-2-氧代乙基]-3H-异吲哚-1-酮
• 职业标准:TWA 0.4 毫克/ 立方米; STEL 1 毫克/ 立方米
• Sigma Aldrich:7803-51-2(sigmaaldrich)