Chlorfenethol 4,4'-二氯-α-甲基二苯基甲醇

CAS 80-06-8 MFCD00000628

化学结构图

80-06-8
SMILES: CC(O)(C1C=CC(Cl)=CC=1)C1C=CC(Cl)=CC=1

化学属性

Mol. FormulaC14H12Cl2O
Mol. Weight267.15
Melting Point68.0 to 71.0 deg-C
Solubility微溶于水，溶于多数有机溶剂。

别名和识别编码

Chemical NameChlorfenethol
Synonym Chlorfenethol {LY} Chlorfenethol {} {LY} Chlorfenethol {} {} {LY} Chlorfenethol {} {} {} {LY} Chlorfenethol {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorfenethol {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00000628
CAS Number80-06-8
PubChem Substance ID87569104
Beilstein Registry Number6(4)4718
EC Number201-246-3
Reaxys-RN2505345
Chemical Name Translation4,4'-二氯-α-甲基二苯基甲醇
Wiswesser Line NotationGR DXQ1&R DG
LabNetwork Molecule IDLN01741871
Canonical SMILESCC(O)(C1=CC=C(C=C1)Cl)C2=CC=C(C=C2)Cl
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分类

  • {SNA} Acaricides, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, C, CH, Chromatography, Environmental Standards, Pesticides & Metabolites, Pesticides Standards
  • {SNA} Acaricides, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, C, CH, Chromatography, Environmental Standards, Pesticides, Pesticides & Metabolites

安全信息

RTECSDC7875000
GHS Symbol
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
WGK Germany2
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Hazard Codes Xn,N
Risk Statements
  • R51/53
  • R22 Harmful if swallowed 吞咽有害
UN Number 3077 2811
Packing GroupIII
Hazard Class9
Storage condition 0-10°C 2-8°C 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 72,304,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SPEADM Special Publication of the Entomological Society of America.  (4603
   Calvert Rd., College Park, MD 20740)  Volume(issue)/page/year: 78-1,15,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 725 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - muscle contraction or spasticity
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   OYYAA2 Oyo Yakuri.  Pharmacometrics.  (Oyo Yakuri Kenkyukai, CPO Box 180,
   Sendai 980-91, Japan) V.1-    1967-  Volume(issue)/page/year: 2,148,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ARSIM* Agricultural Research Service, USDA Information Memorandum.
   (Beltsville, MD 20705)  Volume(issue)/page/year: 20,8,1966

其他信息

  • 储运特性:库房通风低温干燥
  • 类别:农药
  • 农药杀螨剂:杀螨醇又称敌螨，是一种非内吸性杀螨剂，纯品为无色晶体。熔点69.5～70℃。粗制品含邻氯苯异构体、1，1-双氯代苯乙烯和双氯苯酮等杂质。不溶于水，溶于大多数极性有机溶剂。加热后易失水生成1，1-双(4-氯苯基)乙烯，遇强酸不稳定。 制备方法：由4，4′-二氯二苯甲酮与甲基溴化镁反应，再经水处理制得杀螨醇。 用途：农业上用作杀螨剂，用于防治对滴滴涕具有抗药性的害虫，也作为滴滴涕的增效剂。 杀螨醇属低毒农药，大鼠经口LD50为0.93g/kg～5.8g/kg，日本农药注册保留标准规定果品 (夏蜜柑外果皮除外)为3mg/kg。夏蜜柑外果皮为15mg/kg，蔬菜为1mg/kg，茶叶为20mg/kg。FAO/WHO建议日容许摄入量25μg/kg (体重)。现已禁用。
  • 毒性分级:中毒
  • MOL 文件:80-06-8.mol
  • 杀螨醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2692 4,4'-二氯-α-甲基二苯基甲醇 4,4'-Dichloro-alpha-methylbenzhydrol 25G 824元
  • TCI Shanghai:4,4'-二氯-α-甲基二苯基甲醇 4,4'-Dichloro-alpha-methylbenzhydrol,>;98.0%(GC)(80-06-8)
  • MSDS 信息:1,1-双(4-氯苯基)乙醇(80-06-8).msds
  • 外观性质:棕色结晶粉末。
  • 灭火剂:干粉、泡沫、砂土
  • Sigma Aldrich:80-06-8(sigmaaldrich)
  • 可燃性危险特性:可燃; 燃烧产生有毒氯化物气体
  • 急性毒性:口服- 大鼠 LD50: 500 毫克/ 公斤; 腹腔-大鼠 LD50: 725 毫克/公斤

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Acaricides - Pesticides

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