Cumene hydroperoxide 过氧化氢异丙苯

CAS 80-15-9 MFCD00002129

化学结构图

80-15-9
SMILES: CC(C)(OO)c1ccccc1

化学属性

Mol. FormulaC9H12O2
Mol. Weight152.19
Refractive indexn20/D 1.5210
Boiling Point
Density1.03
Flash Point-
TSCAYes
Melting PointNo Data Available
Vapor Density5.4 (vs air)
Vapor Pressure<;0.03 mmHg ( 20 °C)
Solubility略溶于水

别名和识别编码

Chemical NameCumene hydroperoxide
Synonym 1-Methyl-1-phenylethyl hydroperoxide 1-Mmethyl-1-phenylethylhydroperoxide; alpha,alpha-Dimethylbenzylhydroperoxide; Cumene hydroperoxide 1-methy 1-mmethyl-1-phenylethylhydroperoxide 2-Phenyl-2-propyl hydroperoxide 3(2h)isoxazolone,5-(aminomethyl)- 7-Cumyl hydroperoxide 7-Hydroperoxykumen A,A-DIMETHYLBENZYL HYDROPEROXIDE A,A-Dimethylbenzylhydroperoxid ALPHA,ALPHA-DIMETHYLBENZYL HYDROPEROXIDE Alpha,α-dimethylbenzyl hydroperoxide Aztec CHP-80 CUMYL HYDROPEROXIDE Cumene Hydroperoxide (80%, Technical grade) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number80-15-9
PubChem Substance ID87560369
EC Number201-254-7
Beilstein Registry Number1908117
MDL Number-
Reaxys-RN1908117
Chemical Name Translation过氧化氢异丙苯
Wiswesser Line NotationQOX1&1&R
LabNetwork Molecule IDLN00194604
Canonical SMILES-
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分类

  • {SNA} Biochemicals and Reagents, Chemical Synthesis, Enzyme Substrates, Enzymes, Inhibitors, and Substrates, Free Radical Initiators, Glutathione Peroxidase,
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; organic peroxide; 1fragment
  • {SA} Chemical Synthesis, Oxidizing Agents, Peroxides, Synthetic Reagents
  • {SNA} Chemical Synthesis, Enzyme Substrates, Free Radical Initiators, Glutathione Peroxidase, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Substrates by Enzyme, Synthetic Reagents, 材料科学, 生化试剂,
  • {SNA} Biochemicals and Reagents,
  • {SNA} Chemical Synthesis,

相关文献及参考

  • Alternative to tert-Butyl­ hydroperoxide, A13926, in certain catalytic peroxygenation reactions. For example, has been found to give better enantiomeric excesses in the Sharpless-type asymmetric oxidation of sulfides to sulfoxides in the presence of Ti(O-i-Pr)4 and diethyl L-tartrate: Tetrahedron, 43, 5135 (1987); Org. Synth. Coll., 8, 464 (1993); Synlett, 404 (1996).
  • Short: III/35D2
  • Beilstein:6(4)3221

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H302+H312
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 5.2 O,T,N O;T;N
RTECSMX2450000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331+P310
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning {} {} {} {} {} {} {} {TCI}
Safety Statements
  • S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离（生产厂家指定的不相容物质）保存；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S50 Do not mix with ... (to be specified by the manufacturer) 不要与……（由生产厂家指定）混合；
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
Risk Statements
  • R10 Flammable 易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R23 Toxic by inhalation 吸入有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
  • R48/20/22
  • R51/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R7 May cause fire 会导致起火
Storage condition -20 -20°C -20°C, Light sensitive, Light sensitive -20℃ 0-10 0-10°C 2-8°C 储存温度2-8°C
UN Number 2116/3109 3109 UN 3109 5.2 UN3109
Packing GroupII
Hazard Class5.2/8
Warnings 危化品目录(2015) 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8844 mg/kg/67W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   37,825,1966

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 304 mg/kg
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Skin and Appendages - tumors
REFERENCE :
   RARSAM Radiation Research, Supplement.  (New York, NY)  No.1-7, 1959-67.
   Discontinued.  Volume(issue)/page/year: 3,193,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 382 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,242,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1200 mg/kg
TOXIC EFFECTS :
   Cardiac - pulse rate increase, without fall in BP
   Blood - changes in erythrocyte (RBC) count
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 8(8),12,1964

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 26(12),22,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

{hazar

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 44,1989,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 100 ug/plate
REFERENCE :
   PNASA6 Proceedings of the National Academy of Sciences of the United States
   of America.  (National Academy of Sciences, Printing & Pub. Office, 2101
   Constitution Ave., Washington, DC 20418) V.1-    1915-
   Volume(issue)/page/year: 79,7445,1982

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 47 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 308,159,1994

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 203,81,1988

Restrict 危险品

其他信息

  • 类别:氧化剂
  • 用途一:用于乙烯裂解汽油脱砷和ABS接枝聚合引发剂
  • 毒性分级:中毒
  • Acros Organics:过氧化氢异丙苯 Cumyl hydroperoxide, 80%(80-15-9)
  • 蒸气压:<;0.03 mm Hg ( 20 °C)
  • 刺激数据:皮肤-兔子 500 毫克 轻度; 眼睛-兔子 1 毫克
  • Sigma Aldrich:80-15-9(sigmaaldrich)
  • 急性毒性:口服-大鼠 LD50 382 毫克/公斤; 腹注-小鼠 LD50: 270 毫克/公斤
  • 过氧化氢异丙苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80039227 过氧化氢异丙苯（*） 250ml 39元 2011/04/16 C2223 过氧化氢异丙苯(含约20%的芳香烃) Cumene Hydroperoxide (contains ca. 20% Aromatic Hydrocarbon) 100G 225元 2010/06/21 349960050 过氧化氢异丙苯 Cumyl hydroperoxide 80% 5 GR 264元
  • MSDS 信息:过氧化羟基异丙苯(80-15-9).msds
  • TCI Shanghai:过氧化氢异丙苯(含约20%的芳香烃) Cumene Hydroperoxide (contains ca. 20% Aromatic Hydrocarbon)(80-15-9)
  • 外观性质:无色至淡黄色液体。
  • 职业标准:STEL 1 毫克/立方米
  • 上游原料:异丙基苯
  • 可燃性危险特性:易燃; 遇还原剂、铵、有机物、酸、易燃物混合易燃
  • MOL 文件:80-15-9.mol
  • 下游产品:丙酮 --> 苯酚 --> 环氧丙烷 --> 过氧化二异丙苯
  • Alfa Aesar:过氧化羟基异丙苯,tech.80% Cumene hydroperoxide, tech. 80%(80-15-9)
  • 蒸气密度:5.4 (vs air)
  • 储运特性:库房通风低温干燥; 与有机物、还原物、易燃物、强酸分开存放
  • 爆炸物危险特性:与还原剂、硫、磷等混合可爆; 受热、撞击可爆
  • 微溶于水
  • 灭火剂:砂土、二氧化碳、泡沫、化学干粉

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Chromatography Reagents &amp; Solvents - Analytical Reagents
  4. LC-NMR Solvents (CHROMASOLV&reg;) - Chromatography Reagents &amp; Solvents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Perchlorates - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Peroxides - Oxidation
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Free Radical Initiators and Materials for Controlled Radical Polymerization
  5. Organic Peroxides - Free Radical Initiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  4. Free Radical Initiators
  5. Inorganic Peroxides
  1. Functional Group 官能团索引
  2. hydroperoxide
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Enzymes, Inhibitors, and Substrates
  4. Enzyme Substrates
  5. Substrates by Enzyme
  6. Glucuronidase, beta- (selection)

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