Dicumyl Peroxide 过氧化二异丙苯(易制爆)

CAS 80-43-3 MFCD00036227

化学结构图

80-43-3
SMILES: CC(C)(OOC(C)(C)c1ccccc1)c1ccccc1

化学属性

Mol. Formula[C6H5C(CH3)2]2O2
Mol. Weight270.37
Density1.56 g/mL at 25 °C(lit.)
Melting Point39-41 °C(lit.)
Vapor Density9.3 (vs air)
Vapor Pressure15.4 mmHg ( 38 °C)
Boiling Point130 ºC
Solubility不溶
Stability对光敏感

别名和识别编码

Chemical NameDicumyl Peroxide
Synonym Cumene peroxide Varox dcp-T Luperox 500T 过氧化二异丙苯 双(1-甲基-1-苯乙基)过氧化物 双(α,α-二甲基苄基)过氧化物 双(1-甲基-1-苯乙基)过氧化物 双(α,α-二甲基苄基)过氧化物 Luperox 500R Di-Cup 40 KE Di-Cup Active dicumyl peroxide Diisopropylbenzene peroxide Bis(alpha,alpha-dimethylbenzyl)peroxide 双(1-甲基-1-苯基乙基)过氧化物,硫化剂DCP,过氧化二枯茗,二枯茗过氧；过氧化二枯基,二异丙苯过氧化物 Bis(1-methyl-1-phenylethyl) peroxide; Bis(alpha,alpha-dimethylbenzyl)peroxide; DCP 双(1-甲基-1-苯基乙基)过氧化物,硫化剂DCP,过氧化二枯茗,二枯茗过氧；过氧化二枯基,二异丙苯过氧化物;双(1-甲基-1-苯乙基)过氧化物;双(α,α-二甲基苄基)过氧化物 Di-alpha-cumyl peroxide Dicumyl peroxide Peroxide, bis(1-methyl-1-phenylethyl) 双(1-甲基-1-苯乙基)过氧化物 双(α,α-二甲基苄基)过氧化物 过氧化二异丙苯 Di-cupr 过氧化二异丙苯 (Luperox® DCP) Cumyl peroxide Varox dcp-R Isopropylbenzene peroxide
CAS Number80-43-3
PubChem Substance ID24859798
EC Number201-279-3
Beilstein Registry Number2056090
MDL NumberMFCD00036227
Chemical Name Translation过氧化二异丙苯(易制爆)
Wiswesser Line Notation1X1&R&OOX1&1&R
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分类

  • {SNA} Chemical Synthesis, Free Radical Initiators, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Synthetic Reagents, 材料科学
  • Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidation, Peroxi
  • {SNA} Chemical Synthesis, Free Radical Initiators, Materials Science, Organic Peroxides, Oxidizing Agents, Peroxides, Polymer Science, Polymerization Initiators, Reagents for Polymerization, Synthetic Reagents

产品应用

  • 广泛适用于天然胶、合成胶、聚乙烯树脂等高分子材料最优良的引发剂、硫化剂、 交联剂.

相关文献及参考

  • Beilstein: 6,IV,3220

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H242 Heating may cause a fire 加热可能会引起火灾
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 5.2 O,Xi,N
RTECSSD8150000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P410 Protect from sunlight. 防止阳光照射。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P412 Do not expose to temperatures exceeding 50 oC/ 122 oF. 不要暴露在超过50 oC / 122 oF的温度。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P420 Store away from other materials. 远离其他材料。
  • P410+P412
  • P411+P235
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S14 Keep away from ... (incompatible materials to be indicated by the manufacturer) 远离（生产厂家指定的不相容物质）保存；
  • S3/7 Keep container tightly closed in a cool place 将容器严格密闭保存在阴凉处；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R7 May cause fire 会导致起火
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R51/53
UN Number 3110
Storage condition 密封阴凉避光保存，加一定量的水分作为稳定剂。 密封阴凉避光保存，加一定量的水分作为稳定剂。储存温度2-8°C 储存温度2-8°C
Restrict 易制爆危险化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BSPII* SPI Bulletin.  (Soc. of the Plastics Industry, 250 Park Ave., New
   York, NY 10017)  Volume(issue)/page/year: 1/75-19B

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,655,1969

其他信息

  • 见光后逐渐变成微黄色。100℃以上形成高分子化合物，120℃时逐渐分解。溶于乙醇、乙醚、乙酸、苯、异丙苯和石油醚，不溶于水。有氧化性，遇有机物能引起燃烧。低毒，半数致死量(大鼠，经口)4100mg/kg。对眼睛、呼吸系统、皮肤有刺激性。活性氧含量100%为5.92，95%为5.62%。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Perchlorates - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Peroxides - Oxidation
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CH - C
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Free Radical Initiators and Materials for Controlled Radical Polymerization
  5. Organic Peroxides - Free Radical Initiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Peroxides
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  4. Free Radical Initiators
  5. Inorganic Peroxides
  1. Functional Group 官能团索引
  2. peroxide

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