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分类

• {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 12ring; 14ring; 16ring; ketone; 1fragment

相关文献及参考

• Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of structural parameters in structural formula by using different theoretical methods available in the literature.
• Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of n

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 290 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 40,137,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 40,137,1977

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 3300 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 371,123,1996

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 200 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 157,149,1985

其他信息

• Alfa Aesar:7H-苯[脱]蒽-7-酮,99% 7H-Benz[de]anthracen-7-one, 99%(82-05-3)
• 用途一:用于制深色的还原染料
• MSDS 信息:苯并蒽酮(82-05-3).msds
• 毒性分级:高毒
• TCI Shanghai:苯并蒽酮 Benzanthrone,>;98.0%(GC)(82-05-3)
• 类别:易燃固体
• 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
• 外观性质:淡黄色针状结晶。
• 急性毒性:腹腔-大鼠 LD50: 1500 毫克/公斤; 腹腔-小鼠 LD50: 290 毫克/公斤
• 下游产品:还原黑8 --> 还原深蓝BO --> 还原绿 3 --> 还原紫1 --> 还原黑 25 --> 还原绿 1 --> 3-溴代苯绕蒽酮 --> 3,9-二溴苯并蒽酮
• 上游原料:硫酸 --> 苯 --> 铁粉 --> 锌粉 --> 苯酐 --> 硫酸铜 --> 丙烯醛 --> 蒽醌 --> 硫酸铜五水合物 --> 蒽酮
• 图谱信息:苯并蒽酮(82-05-3)核磁图( 13 CNMR) 苯并蒽酮(82-05-3)质谱(MS) 苯并蒽酮(82-05-3)核磁图( 1 HNMR) 苯并蒽酮(82-05-3)红外图谱(IR1) 苯并蒽酮(82-05-3)红外图谱(IR2)
• 可燃性危险特性:受热较易燃; 燃烧产生刺激烟雾
• 方法一:由蒽醌和甘油经下述步骤反应而得。（1）蒽醌在硫酸铜存在下，用铁粉还原生成羟基蒽酮。（2）甘油在浓硫酸作用下失去水分转变为丙烯醛。（3）在硫酸存在下，羟基蒽醌和丙烯醛加合，并失去一分子水形成新环。（4）再用硫酸氧化成苯并蒽酮。原料消耗定额：蒽醌（98%）900kg/t、甘油600kg/t、锌粉440kg/t、硫酸铜（96%）205kg/t、硫酸（100%）5000kg/t。
• 用途二:重要的染料中间体，用于生产还原艳绿FFB、还原橄榄绿B、还原橄榄T、还原灰M、还原黑BBN等。
• 刺激数据:皮肤-兔子 500 毫克/24小时 轻度; 眼睛-兔子 100 毫克/24小时 中度
• Sigma Aldrich:82-05-3(sigmaaldrich)
• MOL 文件:82-05-3.mol
• 储运特性:通风低温干燥; 与库房食品原料, 氢氧化钾, 硝基苯分开存放
• 苯并蒽酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0019 苯并蒽酮 Benzanthrone 500G 2670元 2014/06/02 B0019 苯并蒽酮 Benzanthrone 25G 298元 2010/05/25 B25322 7H-苯[脱]蒽-7-酮, 99% 7H-Benz[de]anthracen-7-one, 99% 25g 487元