Trimethylboroxine 三甲基硼氧六环

CAS 823-96-1 MFCD00013354

化学结构图

823-96-1
SMILES: CB1OB(C)OB(C)O1

化学属性

Mol. Formula(CH3BO)3
Mol. Weight126
Density0.89
Refractive indexn20/D 1.362(lit.)
Boiling Point78-80
Melting Point-38
Flash Point-20°C(lit.)
TSCANo
Appearance 无色至淡黄色液体

别名和识别编码

Chemical NameTrimethylboroxine
Synonym 2,4,6-Trimethyl-cyclotriboroxane Trimethylboroxine TRIMETHYLBOROXINE 2,4,6-Trimethyl-1,3,5-trioxa-2,4,6-triboracyclohexane trimethylboroxin,mbx,intetrahydrofuran 三甲基环三硼氧烷 Boroxin, 2,4,6-trimethyl- Trimethylboroxine, 50 wt% solution in THF Methylboric anhydride METHYLBOROXIN Boroxin, 2,4,6-trimethyl- trimethylboroxin, Trimethylboroxin, in tetrahydrofuran C3H9B3O3 Boroxin, trimethyl- 三甲基环氧硼烷 三甲基硼氧环烷 2,4,6-Trimethylboroxin 三甲基硼氧六环 三甲基环三硼氧烷50%THF溶液 Methaneboronic anhydride
CAS Number823-96-1
EC Number250-023-7
Beilstein Registry Number1757008
MDL NumberMFCD00013354
PubChem Substance ID574072
Chemical Name Translation三甲基硼氧六环
Reaxys-RN1757008
InChIInChI=1S/C3H9B3O3/c1-4-7-5(2)9-6(3)8-4/h1-3H3
LabNetwork Molecule IDLN00223020
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分类

  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Others
  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Other Boronic Acids and Derivatives
  • {SNA} Boronic Acids and Derivatives, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Organometallic Reagents, Other Boronic Acids and Derivatives
  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; alicycle; 6RingOnly; 6ring; 1fragment

产品应用

  • GLC分析的衍生试剂.

相关文献及参考

  • Beilstein: 4,IV,4378
  • Short: III/35E
  • Short: III/35A

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S3 Keep in a cool place 保存在阴凉处；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 F,C F,C,Xi F;Xi
UN Number 2924 UN2924
Packing GroupII
Storage condition 0-10°C Air & Moisture Sensitive Flammables area
Hazard Class3/8

其他信息

  • 下游产品:(S)-2-甲基-CBS-恶唑硼烷
  • MOL 文件:823-96-1.mol
  • 三甲基环三硼氧烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 297520250 三甲基环三硼氧烷 Trimethylboroxine , 3.5M (50 wt.%) solution in THF 25 ML 2674元 2010/06/21 297521000 三甲基环三硼氧烷 Trimethylboroxine , 3.5M (50 wt.%) solution in THF 100 ML 6068元 2010/06/21 429191000 三甲基环三硼氧烷 Trimethylboroxine , 3.5M (50 wt.%) solution in THF, AcroSeal® 100 ML 5851元
  • F:2-10-21
  • 用途一:GLC分析的衍生试剂.

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Alkylation & Esterification - Derivatization Reagents GC
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Others - Boronic Acids and Derivatives
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Others - Boronic Acids and Derivatives

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