4-Phenoxyphenol 4-苯氧基苯酚

CAS 831-82-3 MFCD00002331

化学结构图

831-82-3
SMILES: Oc1ccc(Oc2ccccc2)cc1

化学属性

Mol. FormulaC12H10O2
Mol. Weight186.21
Melting Point80-84°C
Flash Point170°C
TSCAYes
Boiling Point177-180 °C at 11 mmHg
Solubility不溶
Appearance 4-羟基二苯醚纯品为白色结晶，m.p. 85～86℃，b.p. 177～180℃(1.46kPa)，不溶于水，溶于苯、乙醚等有机溶剂。

别名和识别编码

Chemical Name4-Phenoxyphenol
Synonym 4-Phenoxyphenol {LY} 4-Phenoxyphenol {} {LY} 4-Phenoxyphenol {} {} {LY} 4-Phenoxyphenol {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Phenoxyphenol {} {} {} {} {} {} {} {
CAS Number831-82-3
PubChem Substance ID87575067
EC Number212-611-1
Beilstein Registry Number6(2)841
MDL NumberMFCD00002331
Reaxys-RN2047182
Chemical Name Translation4-苯氧基苯酚
LabNetwork Molecule IDLN00197821
InChIInChI=1S/C12H10O2/c13-10-6-8-12(9-7-10)14-11-4-2-1-3-5-11/h1-9,13H
Canonical SMILESOC1=CC=C(OC2=CC=CC=C2)C=C1
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 氨基甲酸酯类杀虫剂
  • {SA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Beil. 6 ,IV,5724
  • Aldrich MSDS 1 , 1452:C / Corp MSDS 1 (2), 2751:D / FT-IR 1 (1), 1115:C / FT-IR 2 (2), 1901:D / FT-NMR 1 (2), 316:B / NMR-Reference 2 (1), 914:D / RegBook 1 (1), 1307:F / Structure Index 1 , 199:D:7 / Vapor Phase 3 , 1044:B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
  • P305+P351+P338
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 方法一:4-羟基二苯醚的制备方法很多，其中两条工艺路线原料成本低，工艺简单。 对苯二酚与溴苯反应 以对苯二酚为原料，加入二甲基亚砜溶剂及96％氢氧化钾溶液，同时通入氮气，搅拌下加热至140℃时，缓慢滴加溴苯溶液，在(145±5)℃温度下反应8h；反应完毕，水相经盐酸酸化，析出结晶，收率为88％～89％。 对氯苯酚法 向装有温度计、分水器和磁力搅拌器的500mL三口瓶中加入235g(2.50mol)苯酚、42.1g(0.75mol)氢氧化钠和150mL甲苯，加热分出水。脱溶剂后，加入1.75g铜盐作催化剂，滴加64.3g(0.50 mol)对氯苯酚，在175℃下反应8h。回收苯酚后，用稀盐酸进行酸化。用乙醚提取，用水洗。干燥后蒸馏，收集145～152℃(800Pa)馏分，得产品60g，收率64%，m. p. 83～84℃(文献值m. p. 85～86℃)。
  • 用途一:用于高效、低毒农药双氧威、蚊蝇醚的合成
  • 4-苯氧基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0950 4-苯氧基苯酚 4-Phenoxyphenol 500G 6700元 2014/06/02 P0950 4-苯氧基苯酚 4-Phenoxyphenol 25G 847元 2010/06/21 213310250 4-苯氧基苯酚 4-Phenoxyphenol 99% 25 GR 1481元
  • 图谱信息:4-苯氧基苯酚(831-82-3)核磁图( 1 HNMR) 4-苯氧基苯酚(831-82-3)红外图谱(IR1) 4-苯氧基苯酚(831-82-3)核磁图( 13 CNMR) 4-苯氧基苯酚(831-82-3)红外图谱(IR2) 4-苯氧基苯酚(831-82-3)质谱(MS)
  • 上游原料:二甲基亚砜 --> 溴苯 --> 1,4-苯二酚 --> 氢氧化钾溶液 --> 分水器 --> 磁力搅拌器
  • 检测方法:GC
  • 海关编码:29095090
  • Acros Organics:4-苯氧基苯酚 4-Phenoxyphenol, 99%(831-82-3)
  • color:colorless to light brown
  • Alfa Aesar:4-苯氧基苯酚,99% 4-Phenoxyphenol, 99%(831-82-3)
  • Hazard Note:Irritant
  • TCI Shanghai:4-苯氧基苯酚 4-Phenoxyphenol,>;95.0%(GC)(831-82-3)
  • MOL 文件:831-82-3.mol
  • Sigma Aldrich:831-82-3(sigmaaldrich)
  • MSDS 信息:Hydroquinone monophenyl ether(831-82-3).msds
  • 用途二:4-羟基二苯醚又名4-苯氧基苯酚，是氨基甲酸酯类杀虫剂双氧威、卫生杀虫剂吡丙醚等的中间体。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C9 to C20+ - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds

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