(S)-(–)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether (S)-(-)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚

CAS 848821-58-9 MFCD08690083

化学结构图

848821-58-9
SMILES: C[Si](C)(C)OC(c1ccccc1)(c1ccccc1)[C@@H]1CCCN1

化学属性

Mol. FormulaC20H27NOSi
Mol. Weight326
Density1.0459 g/mL at 25 °C
Refractive index1.5480 to 1.5520
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Name(S)-(–)-α,α-Diphenyl-2-pyrrolidinemethanol trimethylsilyl ether
Synonym (2S)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine, (S)-,-Diphenylprolinol trimethylsilyl ether, (S)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine (2S)-2-[二苯基[(三甲基硅酯)氧基]甲基]吡咯烷 (S)-α,α-二苯基脯氨醇三甲基硅基醚 (S)-2-[二苯基(三甲基硅烷氧基)甲基]吡咯烷 (2S)-2-[二苯基[(三甲基硅酯)氧基]甲基]吡咯烷，溶于甲苯的 0.05M 溶液 (S)-α,α-二苯基脯氨醇三甲基硅基醚，溶于甲苯的 0.05M 溶液 (S)-2-[二苯基(三甲基硅烷氧基)甲基]吡咯烷，溶于甲苯的 0.05M 溶液 (2S)-2-[二苯基[(三甲基硅酯)氧基]甲基]吡咯烷，溶于甲苯的 0.05M 溶液 (S)-α,α-二苯基脯氨醇三甲基硅基醚，溶于甲苯的 0.05M 溶液 (S)-2-[二苯基(三甲基硅烷氧基)甲基]吡咯烷，溶于甲苯的 0.05M 溶液 (S)-(–)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚 (2S)-2-[二苯基[(三甲基硅酯)氧基]甲基]吡咯烷 (S)-2-[二苯基(三甲基硅烷氧基)甲基]吡咯烷 (S)-α,α-二苯基脯氨醇三甲基硅基醚
MDL NumberMFCD08690083
PubChem Substance ID354334880
Chemical Name Translation(S)-(-)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚
CAS Number848821-58-9
Reaxys-RN10089429
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts, Reproducibility: Validated Products, Verified by OrgSyn

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P331 Do NOT induce vomiting.. 不要催吐。
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes F,Xn Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 0-10°C
Restrict -

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Proline-Based Organocatalysts - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Ethers - Organic Building Blocks

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