1,2-Cyclohexanedicarboxylic anhydride 1,2-环己二酸酐

CAS 85-42-7 MFCD00005926

化学结构图

85-42-7
SMILES: O=C1OC(=O)[C@@H]2CCCC[C@H]12

化学属性

Mol. FormulaC8H10O3
Mol. Weight154
Boiling Point158 °C/17 mmHg(lit.)
Melting Point32-34 °C(lit.)
Density1.23
Flash Point151°(303°F)
TSCANo
Stability对空气和湿度敏感

别名和识别编码

Chemical Name1,2-Cyclohexanedicarboxylic anhydride
Synonym cis-Hexahydrophthalic anhydride 六氢邻苯二甲酸酐 1,2-环己二甲酸酐（主要为顺式异构体）
MDL NumberMFCD00005926
CAS Number85-42-7
PubChem Substance ID24847568
EC Number201-604-9
Reaxys-RN83213
Beilstein Registry Number83214
Chemical Name Translation1,2-环己二酸酐
InChIKeyMUTGBJKUEZFXGO-UHFFFAOYSA-N
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Organic Building Blocks
  • {SA} Crosslinking Agents and Additives for Epoxides, Materials Science, Polymer Additives, Polymer Science
  • {SNA} Curing Agents for Epoxides, Materials Science, Polymer Additives, Polymer Science
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; alicycle; large ring; fused rings; 5ring; 6ring; 9ring; carbo-anhydride; 1fragment
  • {SNA} Curing Agents for Epoxides, Polymer Additives, Polymer Science, 材料科学

产品应用

  • 中间体,用于涂料，环氧树脂的固化剂、胶粘剂、增塑剂等。

相关文献及参考

  • Aldrich MSDS 1 , 515:B / Corp MSDS 1 (1), 961:D / FT-IR 2 (1), 1212:C / FT-IR 1 (1), 715:D / FT-NMR 1 (1), 1175:C / IR-Spectra (3), 418:C / IR-Spectra (2), 369:F / NMR-Reference 2 (1), 604:B / RegBook 1 (1), 835:G / Structure Index 1 , 129:D:9
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS2 Title: Corrigendum to the Commission communication pursuant to Article 13 of Council Directive 67/548/EEC of 27 June 1967 on the approximation of the l

安全信息

WGK Germany1
GHS Symbol
Precautionary statements
  • P304+P340
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P305+P351+P338+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338
  • P304+P341
  • P342+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P302+P350
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P304+P340+P342+P311
  • P302+P352+P333+P313+P362+P364
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
Signal word Danger
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H303 May be harmfully swallowed 吞食可能有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Storage condition Moisture Sensitive

其他信息

  • 溶于苯、丙酮等，有吸湿性。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymer Additives - Polymer Science
  4. Crosslinking Agents and Additives for Epoxides - Polymer Additives
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acid Anhydrides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Polymers
  4. Polymer Additives
  5. Chain Transfer Agents
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride

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