Tris(2,6-Dimethoxyphenyl)Phosphine 三(2,6-二甲氧基苯基)磷
CAS 85417-41-0 MFCD00192558
化学结构图
SMILES: COC1C=CC=C(OC)C=1P(C1C(=CC=CC=1OC)OC)C1C(=CC=CC=1OC)OC
化学属性
| Mol. Formula | C24H27O6P |
|---|---|
| Mol. Weight | 442.45 |
| Melting Point | 153.0 to 157.0 deg-C |
| TSCA | No |
| Appearance | white to off-white pwdr. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | Tris(2,6-Dimethoxyphenyl)Phosphine |
|---|---|
| MDL Number | MFCD00192558 |
| Synonym | DMPP TDMPP 三(2,6-二甲氧基苯)膦 |
| EC Number | 000-000-0 |
| CAS Number | 85417-41-0 |
| PubChem Substance ID | 87577367 |
| Chemical Name Translation | 三(2,6-二甲氧基苯基)磷 |
| Reaxys-RN | 4302254 |
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分类
- {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
相关文献及参考
- Preferred ligand employed by Trost in directed tandem Pd-catalyzed reactions as an approach to furans and butenolides: J. Am. Chem. Soc., 117, 7255 (1995).
安全信息
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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