• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} 3D Printing Materials for Research and Deve
• Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis,
• {SNA} Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Methacrylate, Monomers, Organic Building Blocks, Polymer Science
• {SNA} 3D Printing Materials for Research and Development, Acrylic Monomers, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters, Methacrylate, Monomers, Monomers and Polymerization Tools for 3D Printing,

产品应用

• 甲基丙烯酸羟乙酯是一种官能单体，供制备热固性丙烯酸涂料丁苯橡胶乳液改性剂。丙烯酸改性聚氨酯涂料，水溶性电镀涂料粘合剂，纤维整理剂，纸品涂料，感光涂料及聚氯乙烯树脂改性剂等物质用的各种树脂，用途广泛。

相关文献及参考

• Delbressine, L., et al.: Xenobiotica, 11, 241 (1981),
• Gerberick, G., et al.: Toxicol. Sci., 97, 417 (2007),
• Beil. 2 ,IV,1530
• Aldrich MSDS 1 , 1059:B / Corp MSDS 1 (1), 1922:D / FT-IR 1 (1), 665:B / FT-IR 2 (1), 1090:B / FT-NMR 1 (1), 1045:A / IR-Spectra (3), 390:A / IR-Spectra (2), 345:F / NMR-Reference 2 (1), 560:C / RegBook 1 (1), 753:M / Sax 6 , 1344 / Sigma FT-IR 1 (2), 625:D / Structure Index 1 , 116:A:9 / Vapor Phase 3 , 720:D

安全信息

GHS Symbol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 99200 nL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 63,376,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 497 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 62,778,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 36,58,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 4680 mg/kg
TOXIC EFFECTS :
   Behavioral - coma
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 1130

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3062 mg/kg
SEX/DURATION            : male 35 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(11),81,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3062 mg/kg
SEX/DURATION            : female 35 week(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 52(11),81,1987

其他信息

• TCI Shanghai:甲基丙烯酸-2-羟基乙酯(含稳定剂甲氧基氢醌) 2-Hydroxyethyl Methacrylate (stabilized with MEHQ),>;95.0%(GC)(868-77-9)
• 海关编码:29161490
• 方法一:1.由环氧乙烷与甲基丙烯酸反应而得。在甲基丙烯酸中加入硫氰酸铁、四甲基氯化铵等及少许对苯二酚，搅拌加热至90℃，在氮气保护下，通入环氧乙烷气体反应约2h。将反应产物冷至60℃，加少量对苯二酚后减压蒸馏，收集86-89℃（0.67kPa）馏分即得成品，收率80%以上。2.甲基丙烯酸钾盐与氯乙醇在阻聚剂存在下反应生成粗甲基丙烯酸-2-羟基乙酯，经盐析、精制得成品。
• 用途二:主要用于树脂及涂料的改性。与其他丙烯酸类单体共聚，可制得侧链含有活性羟基的丙烯酸树脂，可进行酯化反应和交联反应，合成不溶性树脂和提高粘接性，可用作纤维处理剂等。与三聚氰胺-甲醛（或脲醛）树脂、环氧树脂等共同反应，用于制造双组分涂料。加入高级轿车油漆中，可长期保持镜面光泽。还可用作合成纺织物的胶粘剂和医用高分子单体等。
• 甲基丙烯酸羟乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30039880 4-氯-3，5-二硝基苯甲酸;3,5-二硝基-4-氯苯甲酸 10g 114元 2011/08/23 30039881 4-氯-3，5-二硝基苯甲酸;3,5-二硝基-4-氯苯甲酸 25g 300.3元 2011/08/23 TM008501 甲基丙烯酸-2-羟乙酯 500g 360元
• 图谱信息:甲基丙烯酸羟乙酯(868-77-9)红外图谱(IR1) 甲基丙烯酸羟乙酯(868-77-9)Raman光谱 甲基丙烯酸羟乙酯(868-77-9)质谱(MS) 甲基丙烯酸羟乙酯(868-77-9)红外图谱(IR2)
• F:8
• 蒸气密度:5 (vs air)
• 易燃，溶于水，溶于通常的有机溶液剂，极易聚合
• 外观性质:无色透明液体。
• 蒸气压:0.01 mm Hg ( 25 °C)
• 用途三:甲基丙烯酸羟乙酯是一种官能单体，供制备热固性丙烯酸涂料丁苯橡胶乳液改性剂。丙烯酸改性聚氨酯涂料，水溶性电镀涂料粘合剂，纤维整理剂，纸品涂料，感光涂料及聚氯乙烯树脂改性剂等物质用的各种树脂，用途广泛。
• Sigma Aldrich:868-77-9(sigmaaldrich)
• Alfa Aesar:2-羟基乙基甲基丙烯酸盐,97%,stab.withca500ppm4-methoxyphenol 2-Hydroxyethyl methacrylate, 97%, stab. with ca 500ppm 4-methoxyphenol(868-77-9)
• 上游原料:曙光红(四溴荧光素) --> 1,4-苯二酚 --> 2-氯乙醇 --> 2-甲基丙烯酸 --> 阻聚剂 --> 四甲基氯化铵
• MSDS 信息:甲基丙烯酸2-羟乙酯(868-77-9).msds
• 检测方法:GC,NMR
• Acros Organics:甲基丙烯酸2-羟乙酯 2-Hydroxyethyl methacrylate, stabilized, 96%(868-77-9)
• MOL 文件:868-77-9.mol
• 用途一:用于合成医用高分子材料、热固性涂料及粘合剂等
• 敏感性:Air Sensitive