Methyl dimethoxyacetate 二甲氧基乙酸甲酯

CAS 89-91-8 MFCD00008484

化学结构图

89-91-8
SMILES: COC(=O)C(OC)OC

化学属性

Mol. FormulaC5H10O4
Mol. Weight134.13
Density1.096
Boiling Point169°C at 760 mmHg
Refractive index1.4030 to 1.4070
Flash Point67°C
TSCAYes
Stability对湿度敏感

别名和识别编码

Chemical NameMethyl dimethoxyacetate
Synonym 2,2-dimethoxyaceticacidmethylester 2,2-二甲氧基乙酸甲酯 Acetic acid, dimethoxy-, methyl ester Aceticacid,dimethoxy-,methylester Dimethoxyacetic acid methyl ester METHYL DIMETHOXYACETATE METHYL GLYOXALATE DIMETHYL ACETAL Methyl 2,2-dimethoxyacetate Methyl Dimethoxyacetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number1757582
PubChem Substance ID66647
CAS Number89-91-8
EC Number201-950-0
MDL NumberMFCD00008484
Reaxys-RN1757582
Chemical Name Translation二甲氧基乙酸甲酯
InChIKeyNZTCVGHPDWAALP-UHFFFAOYSA-N
LabNetwork Molecule IDLN00224107
InChIInChI=1S/C5H10O4/c1-7-4(6)5(8-2)9-3/h5H,1-3H3
Canonical SMILESO=C(OC)C(OC)OC
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {SA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

相关文献及参考

  • 3. Synth. Commun. 23 , 1003, (1993)
  • Addition of the Li derivative to carbonyl compounds provides a route to 2,2-dimethoxy-3-hydroxy esters: Tetrahedron Lett., 2825 (1977). Similarly, alkylation gives the acetals of ɑ-keto esters: Synthesis, 33 (1979). See also Ethyl­ diethoxyacetate, L00390.
  • Short: EINECS
  • Short: III/35E

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (EU), half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Signal word Warning
GHS Symbol
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Storage condition +4°C 0-6°C 2-8°C 4℃ Moisture Sensitive Store at room temperature 对潮湿敏感,密封干燥保存.

其他信息

  • 二甲氧基乙酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0503 二甲氧基乙酸甲酯 Methyl Dimethoxyacetate 25ML 1200元 2014/06/02 D0503 二甲氧基乙酸甲酯 Methyl Dimethoxyacetate 10ML 689元 2010/06/21 414180250 二甲氧基乙酸甲酯 Methyl dimethoxyacetate 98% 25 GR 1445元
  • 图谱信息:二甲氧基乙酸甲酯(89-91-8)核磁图( 13 CNMR) 二甲氧基乙酸甲酯(89-91-8)核磁图( 1 HNMR) 二甲氧基乙酸甲酯(89-91-8)质谱(MS) 二甲氧基乙酸甲酯(89-91-8)红外图谱(IR1)
  • MSDS 信息:Methyl dimethoxyacetate(89-91-8).msds
  • Sigma Aldrich:89-91-8(sigmaaldrich)
  • MOL 文件:89-91-8.mol
  • Alfa Aesar:二甲氧基乙酸甲酯,97+% Methyl dimethoxyacetate, 97+%(89-91-8)
  • 用途一:有机合成,手性药物的合成
  • TCI Shanghai:二甲氧基乙酸甲酯 Methyl Dimethoxyacetate,>;95.0%(GC)(89-91-8)
  • 敏感性:Moisture Sensitive
  • Acros Organics:二甲氧基乙酸甲酯 Methyl dimethoxyacetate, 99%(89-91-8)

系列性分类


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