2-(Bromomethyl)phenylboronic acid 2-(溴甲基)苯硼酸
CAS 91983-14-1 MFCD01318941
化学结构图
SMILES: OB(O)C1C=CC=CC=1CBr
化学属性
| Mol. Formula | C7H8BBrO2 |
|---|---|
| Mol. Weight | 214.85 |
| Melting Point | 145-148° |
| TSCA | No |
别名和识别编码
| Chemical Name | 2-(Bromomethyl)phenylboronic acid |
|---|---|
| CAS Number | 91983-14-1 |
| Alfabeta Name | BROMOMETHYLPHENYLBORONICACID 2- |
| MDL Number | MFCD01318941 |
| Synonym | 2-溴甲基苯基硼酸 α-Bromo-o-tolueneboronic acid o-Boronobenzyl bromide 2-(溴甲基)苯硼酸 2-(Bromomethyl)benzeneboronic acid 95% 2-Boronobenzyl bromide RARECHEM AH PB 0060 2-溴甲基苯硼酸 2-(Bromomethyl)phenylboronic acid 2-Bromomethylphenylboronic α-Bromo-o-tolueneboronic acid o-Boronobenzyl bromide 2-溴乙基基苯硼酸 2-(BROMOMETHYL)BENZENEBORONIC ACID 2-BROMOMETHYLPHENYLBORONIC ACID 2-溴苄苯硼酸 |
| PubChem Substance ID | 125307977 |
| Reaxys-RN | 2965283 |
| Beilstein Registry Number | 16(4)1672 |
| Chemical Name Translation | 2-(溴甲基)苯硼酸 |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. M. Kitamura, et al., , 11B NMR Sensing of d-Block Metal Ions in Vitro and in Cells Based on the Carbon-Boron Bond Cleavage of Phenylboronic Acid-Pendant Cyclen (Cyclen = 1,4,7,10-Tetraazacyclododecane) Inorg. Chem. 50 , 11568-11580, (2011)
- 2. L. Feng, et al., , A highly sensitive water-soluble system to sense glucose in aqueous solution Org. Biomolecular Chem. 9 , 2938-2942, (2011)
- 3. Z. Sharrett, et al., , Boronic acid-appended bis-viologens as a new family of viologen quenchers for glucose sensing Tetrahedron Lett. 49 , 300-304, (2008)
- 4. S. Gamsey, et al., , Boronic Acid-Based Bipyridinium Salts as Tunable Receptors for Monosaccharides and a-Hydroxycarboxylates J. Am. Chem. Soc. 129 , 1278-1286, (2007)
- 5. D. E. Morrison, et al., , Boronated phosphonium salts containing arylboronic acid, closo-carborane, or nido-carborane: synthesis, x-ray diffraction, in vitro cytotoxicity, and cellular uptake J. Biol. Inorg. Chem. 15 , 1305-1318, (2010)
- 6. S. Kim, et al., , New fluorescent and colorimetric chemosensors based on the rhodamine and boronic acid groups for the detection of Hg2+ Tetrahedron Lett. 51 , 3286-3289, (2010)
- 7. Z. Xu, et al., , Ratiometric Fluorescence Sensing of Fluoride Ions by an Asymmetric Bidentate Receptor Containing a Boronic Acid and Imidazolium Group Eur. J. Org. Chem. 18 , 3058-3065, (2009)
- 8. X. Yu, et al., , Microwave-assisted synthesis and biological activities of 9-boronobenzyladenine derivatives J. Chem. Res. (M) 6 , 347-349, (2007)
安全信息
GHS Symbol
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P304+P340
- P304+
- H290 May be corrosive to metals 可能腐蚀金属。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- Hazard Note:Irritant
- Sigma Aldrich:91983-14-1(sigmaaldrich)
- MOL 文件:91983-14-1.mol
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