4-Bromobiphenyl 4-溴代联苯

CAS 92-66-0 MFCD00000100

化学结构图

92-66-0
SMILES: Brc1ccc(-c2ccccc2)cc1

化学属性

Mol. FormulaC12H9Br
Mol. Weight233.10
Density0.9327
Boiling Point310°C at 760 mmHg
Melting Point82-86°C
TSCAT
Flash Point>100°C
Solubility不溶
Appearance 无色片状结晶。熔点91.5-92℃（89.5-90℃)，沸点310℃，闪点143℃，相对密度0.9327（25/4℃）。溶于醇、醚、二硫化碳、苯、四氯化碳和丙酮，微溶于乙酸，不溶于水。有特殊气味。

别名和识别编码

Chemical Name4-Bromobiphenyl
CAS Number92-66-0
EC Number202-176-6
Beilstein Registry Number5(4)1819
MDL NumberMFCD00000100
Reaxys-RN1907453
PubChem Substance ID7101
Alfabeta NameBROMOBIPHENYL 4-
Synonym 4-Bromobiphenyl {LY} 4-Bromobiphenyl {} {LY} 4-Bromobiphenyl {} {} {LY} 4-Bromobiphenyl {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromobiphenyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation4-溴代联苯
LabNetwork Molecule IDLN00120892
InChIInChI=1S/C12H9Br/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H
Canonical SMILESBrC1=CC=C(C2=CC=CC=C2)C=C1
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分类

  • {Chemicalbook} 农药中间体: 杀鼠剂中间体
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Aryl, Building Blocks, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 用于合成有机中间体（医药、液晶、农药）

相关文献及参考

  • Short: III/35D2
  • Short: III/20b
  • Beilstein:5(4)1819

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R50/53
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
RTECSDV1750100
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Warnings IRRITANT
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 9
UN Number 3152 UN 3152 9/PG 2
Packing GroupIII
Storage condition 2-8°C, sealed storage, away from moisture and light {LY} 2-8°C, sealed storage, away from moisture and light {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moistur 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   27,1245,1978

其他信息

  • 灭火剂:水,干粉,二氧化碳,泡沫,沙土
  • 储运特性:库房低温通风干燥
  • 图谱信息:4-溴代联苯(92-66-0)核磁图( 1 HNMR) 4-溴代联苯(92-66-0)质谱(MS) 4-溴代联苯(92-66-0)核磁图( 13 CNMR) 4-溴代联苯(92-66-0)红外图谱(IR1) 4-溴代联苯(92-66-0)红外图谱(IR2)
  • 用途一:用于液晶原料及中间体
  • Hazard Note:Irritant
  • 可燃性危险特性:热分解排出有毒溴化物烟雾
  • MOL 文件:92-66-0.mol
  • 方法一:其制备方法是将联苯溶于85％乙酸中，在该溶液中加入溴，避光在常温下搅拌反应，然后用溶剂萃取，蒸去溶剂得产品。 也可以在β-糊精存在下，用联苯与溴进行气-固反应而得到4-溴联苯。
  • 4-溴代联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010291 对溴联苯 100g 300元 2011/04/16 B1330 4-溴联苯 4-Bromobiphenyl 25G 710元 2011/04/16 B1330 4-溴联苯 4-Bromobiphenyl 250G 3830元
  • 海关编码:29036990
  • TSCA:T
  • 用途四:用于合成有机中间体（医药、液晶、农药）
  • 类别:有毒物质
  • MSDS 信息:4-Bromobiphenyl(92-66-0).msds
  • Sigma Aldrich:92-66-0(sigmaaldrich)
  • 用途二:4-溴联苯是杀鼠剂溴鼠灵、溴敌隆的中间体。
  • TCI Shanghai:4-溴联苯 4-Bromobiphenyl,>;95.0%(GC)(92-66-0)
  • 用途三:有机合成中间体。
  • 稍具芳香气味。溶于乙醇、乙醚、二硫化碳、苯、四氯化碳和丙酮，微溶于乙酸，不溶于水。
  • Acros Organics:4-溴联苯 4-Bromobiphenyl, 99%(92-66-0)
  • 方法二:由对溴苯胺经下述反应而得。将水、对溴苯胺和浓盐酸一起冷却，保持在0-5℃慢慢加入亚硝酸钠水溶液，进行重氮化至淀粉碘化钾试纸呈蓝色，滤出澄清的重氮液。将苯加入重氮液，在5-10℃搅拌半小时，同时慢慢滴加氢氧化钠溶液，加完后继续搅拌3h，再在室温下搅拌45h。分出苯层，用水洗涤，蒸出苯后进行减压蒸馏，收集170-175℃（1.06kPa）馏分，用乙醇重结晶，得熔点90℃的成品。
  • Alfa Aesar:4-溴联苯,98+% 4-Bromobiphenyl, 98+%(92-66-0)
  • 上游原料:联苯 --> 糊精 --> 4-溴苯胺 --> 淀粉-碘化钾试纸
  • 下游产品:溴敌隆 --> 溴鼠灵 --> 1-(4'-溴联苯-4-基)-3-苯基-2-丙烯-1-酮

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C9 to C12 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Imines/Amidines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C8

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