3,4-Epoxy-1-Butene 3,4-环氧-1-丁烯

CAS 930-22-3 MFCD00005149

化学结构图

930-22-3
SMILES: C=CC1CO1

化学属性

Mol. FormulaC4H6O
Mol. Weight70.09
Refractive index1.4150 to 1.4190
Boiling Point67°C(lit.)
Density0.870
Flash Point-50°C
TSCAYes
Melting Point-135°C

别名和识别编码

Chemical Name3,4-Epoxy-1-Butene
Synonym (±)-Vinyloxirane 1,2-EB 1,2-EPOXY-3-BUTENE 1,2-Epoxy-3-butene 1,2-Epoxy-3-butylene 1,2-Epoxybutene-3 1,2-epoxybutene 1,2-epoxybutene-3 1,3-BUTADIENE MONOEPOXIDE 1,3-Butadiene Monoepoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number930-22-3
PubChem Substance ID13586
EC Number213-210-4
Beilstein Registry Number17(1)13
MDL NumberMFCD00005149
Reaxys-RN103170
Chemical Name Translation3,4-环氧-1-丁烯
Wiswesser Line NotationT3OTJ B1U1
LabNetwork Molecule IDLN01742192
InChIInChI=1S/C4H6O/c1-2-4-3-5-4/h2,4H,1,3H2
Canonical SMILESC=CC1CO1
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {uni_hamburg} no charge; oxygen heterocycle; alicycle; 3ring; ether; racemate; 1fragment
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Beilstein:17(1)13
  • Reaction with allyl bromide, mediated by In metal, affords diallylmethanol: Tetrahedron Lett., 44, 2911 (2003):
  • Short: II/14a
  • Short: II/2
  • Short: II/25C

安全信息

GHS Symbol
WGK Germany2
Hazard Codes F,Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSEM7350000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P303+P361+P353
  • P305+P351+P338
  • P330 Rinse mouth. 漱口
  • P337+P313
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number UN 1993 3/PG 2 1993
Risk Statements
  • R11 Highly flammable 非常易燃
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
Storage condition 2-8°C 2-8°C, stored under nitrogen Moisture Sensitive 存储温度2-8℃
Packing GroupII
Hazard Class3 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 492 gm/kg/41W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   JNCIAM Journal of the National Cancer Institute.  (Washington, DC)  V.1-60,
   1940-78.  For publisher information, see JJIND8.  Volume(issue)/page/year:
   31,41,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 168 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   52,422,1980

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 80 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 391,233,1997

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Net

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   BBRCA9 Biochemical and Biophysical Research Communications.  (Academic
   Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1959-
   Volume(issue)/page/year: 80,298,1978

TYPE OF TEST            : Micronucleus test
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 1 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 18,168

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 nmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 263,47,1991

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 33300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYP

其他信息

  • F:21
  • Sigma Aldrich:930-22-3(sigmaaldrich)
  • 环氧丁烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0337 1,3-丁二烯单环氧化物 1,3-Butadiene Monoepoxide 5G 1390元 2014/06/02 E0337 1,3-丁二烯单环氧化物 1,3-Butadiene Monoepoxide 1G 474元 2010/06/21 155790010 环氧丁烯 Butadiene monoxide 97% 1 GR 889元
  • 用途一:新型精细化工产品，可以进一步制成1,4－丁二醇、四氢呋喃，环丙胺等产品，在化纤，医药等行业有重要用途。
  • 无色透明至微黄色液体，不溶于水
  • TCI Shanghai:环氧丁烯 1,3-Butadiene Monoepoxide,>;97.0%(GC)(930-22-3)
  • 外观性质:无色透明至微黄色液体，不溶于水密度:0.87 熔点:-135 °C 沸点:65-66 °C 闪点:-50 °C 折光率:1.416-1.42
  • Alfa Aesar:环氧丁烷,98% Butadiene monoxide, 98%(930-22-3)
  • 敏感性:Moisture Sensitive
  • MOL 文件:930-22-3.mol
  • Acros Organics:环氧丁烯 Butadiene monoxide, 97%(930-22-3)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Epoxide Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Carboxylic Acid Monomers

相关产品推荐