4-Methylphenylsulfonyl azide 对甲苯磺酰叠氮

CAS 941-55-9 MFCD00180767

化学结构图

941-55-9
SMILES: Cc1ccc(S(=O)(=O)N=[N+]=[N-])cc1

化学属性

Mol. FormulaC7H8N3O2S
Mol. Weight197
Density0.90
Refractive indexn20/D 1.502
Melting Point22

别名和识别编码

Chemical Name4-Methylphenylsulfonyl azide
Synonym 对甲苯磺酰叠氮化物 溶液 Tosyl azide 4-Methyl-benzenesulfonyl azide 对甲基苯磺酰叠氮 溶液 p-Toluenesulfonyl azide; 4-Methylbenzenesulfonyl azide 对甲苯磺酰叠氮 溶液 4-甲基苯磺酰基叠氮化物 溶液 Benzenesulfonyl azide, 4-methyl- 4-甲基苯磺酰基叠氮化物 溶液 对甲基苯磺酰叠氮 溶液 对甲苯磺酰叠氮化物 溶液
CAS Number941-55-9
EC Number213-381-5
MDL NumberMFCD00180767
Chemical Name Translation对甲苯磺酰叠氮
LabNetwork Molecule IDLN00224038
PubChem Substance ID329763205
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分类

  • {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Synthetic Reagents, Various Azides
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together wit

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H300 Fatal if swallowed 吞食致命
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Signal word Danger Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Hazard Codes F,T+
Risk Statements
  • R11 Highly flammable 非常易燃
  • R28 Very toxic if swallowed 吞咽极毒
  • R38 Irritating to skin 刺激皮肤
  • R48/20
  • R5 Heating may cause an explosion 加热会引起爆炸
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Azides - Nitrogen Compounds

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