Diacetato{(S)-(-)-5,5’-Bis[Di(3,5-Xylyl)Phosphino]-4,4’-Bi-1,3-Benzodioxole}Ruthenium(II) 二乙酸根[(S)-(-)-5,5’-双[二(3,5-二甲苯基)膦基]-4,4’-二-1,3-苯并二噁茂]钌(II)
CAS 944450-50-4 MFCD044450504
化学结构图
SMILES:
化学属性
| Mol. Formula | C50H50O8P2Ru |
|---|---|
| Mol. Weight | 941.94 |
| Appearance | yellow to brownish-red to dark green solid |
| Stability | air sensitive |
| Melting Point | >100°C dec. |
别名和识别编码
| Chemical Name | Diacetato{(S)-(-)-5,5’-Bis[Di(3,5-Xylyl)Phosphino]-4,4’-Bi-1,3-Benzodioxole}Ruthenium(II) |
|---|---|
| Synonym | 二乙酸根[(R)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II) 二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II) |
| MDL Number | MFCD09753025 |
| PubChem Substance ID | 253660976 |
| Chemical Name Translation | 二乙酸根[(S)-(-)-5,5’-双[二(3,5-二甲苯基)膦基]-4,4’-二-1,3-苯并二噁茂]钌(II) |
| CAS Number | 944450-50-4 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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