2,4-Dinitrodiphenylamine 2,4-二硝基二苯胺

CAS 961-68-2 MFCD00007223

化学结构图

961-68-2
SMILES: O=[N+]([O-])c1ccc(Nc2ccccc2)c([N+](=O)[O-])c1

化学属性

Mol. FormulaC12H9N3O4
Mol. Weight259
Melting Point159-161
Solubility溶于热乙醇、热苯、丙酮、氯仿。

别名和识别编码

Chemical Name2,4-Dinitrodiphenylamine
Synonym 2,4-DINITRODIPHENYLAMINE 2,4-Dinitro-N-phenylaniline 2,4-Dinitro-diphenylamine 2,4-Dinitrodiphenylamine 2,4-dinitro-N-phenyl-Benzenamine 2,4-dinitro-N-phenyl-benzenamine 2,4-dinitro-diphenylamin 2,4-dinitro-n-phenyl-benzenamin 2,4-二硝基二苯胺 2,4-二硝基联苯胺 2，4-二硝基二苯胺 o,p-Dinitrodiphenylamine Benzenamine,2,4-dinitro-N-phenyl- C.I. Disperse Yellow 14 Diphenylamine, 2,4-dinitro- N-(2,4-Dinitrophenyl)-N-phenylamine N-(2,4-Dinitrophenyl)Aniline N-(2,4-Dinitrophenyl)aniline N-(2,4-Dinitrophenyl)benzenamine N-Phenyl-2,4-dinitroaniline acetochinongelb 5JZ disperse yellow 14 disperseyellow14
MDL NumberMFCD00007223
CAS Number961-68-2
PubChem Substance ID13748
Beilstein Registry Number8588595
EC Number213-508-4
Reaxys-RN1996954
Chemical Name Translation2,4-二硝基二苯胺
InChIKeyRHTVQEPJVKUMPI-UHFFFAOYSA-N
Wiswesser Line NotationWNR CNW DMR
LabNetwork Molecule IDLN01360034
InChIInChI=1S/C12H9N3O4/c16-14(17)10-6-7-11(12(8-10)15(18)19)13-9-4-2-1-3-5-9/h1-8,13H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Amines, Building Blocks, C12, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Short: III/35C1 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 1: Aliphatic and Aromatic Hydrocarbons, Steroids, Carbohydrates Author: Gupta, R.R.; Jain, M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C1 Year: 2000 ISBN: 3-540-66780-6 ISBN: 978-3-540-66780-3 Internet Resource: DOI:10.1007/b60149 RefComment: VII, 310 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H316 Causes mild skin irritation 会轻微的刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSJJ8825000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#06394

其他信息

  • MSDS 信息:2,4-二硝基二苯胺(961-68-2).msds
  • 可燃性危险特性:明火可燃;受热分解有毒氮氧化物烟雾;与氧化剂反应
  • Sigma Aldrich:961-68-2(sigmaaldrich)
  • MOL 文件:961-68-2.mol
  • Acros Organics:2,4-二硝基二苯 2,4-Dinitrodiphenylamine, 98%(961-68-2)
  • TCI Shanghai:2,4-二硝基-N-苯基苯胺 2,4-Dinitrodiphenylamine,>;96.0%(T)(961-68-2)
  • 方法一:2,4-二硝基氯苯和苯胺按等摩尔比加入水中，先在60℃搅拌反应2h，再在90℃搅拌反应2h。冷却，过滤，洗涤，干燥，得2,4-二硝基二苯胺，收率95-98%。
  • 毒性分级:中毒
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土。
  • 用途一:有机合成中间体。
  • 图谱信息:2,4-二硝基二苯胺(961-68-2)核磁图( 1 HNMR) 2,4-二硝基二苯胺(961-68-2)红外图谱(IR1) 2,4-二硝基二苯胺(961-68-2)质谱(MS) 2,4-二硝基二苯胺(961-68-2)核磁图( 13 CNMR) 2,4-二硝基二苯胺(961-68-2)红外图谱(IR2)
  • 上游原料:2,4-二硝基氯苯
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
  • 外观性质:红色针状结晶。
  • 急性毒性:静脉-小鼠 LD50: 180 毫克/公斤
  • 2,4-二硝基二苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0278 2,4-二硝基二苯胺 2,4-Dinitrodiphenylamine 500G 1950元 2014/06/02 D0278 2,4-二硝基二苯胺 2,4-Dinitrodiphenylamine 25G 299元 2010/06/21 152555000 2,4-二硝基二苯胺 2,4-Dinitrodiphenylamine 98% 500 GR 1059元
  • 类别:有毒物品

系列性分类

  1. C12 - Amines
  1. C14 to C16 - Amines

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