(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl rac-BINAP

CAS 76189-55-4 MFCD76189554

化学结构图

76189-55-4
SMILES: c1ccc(P(c2ccccc2)c2ccc3ccccc3c2-c2c(P(c3ccccc3)c3ccccc3)ccc3ccccc23)cc1

化学属性

Mol. FormulaC44H32P2
Mol. Weight622.67
Appearance white to off-white pwdr.
Melting Point239-242°C
Boiling Point724.3±55.0 °C at 760 mmHg

别名和识别编码

Chemical Name(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
Chemical Name Translationrac-BINAP
Synonym (R)-BINAP {LY} (R)-BINAP {} {LY} (R)-BINAP {} {} {LY} (R)-BINAP {} {} {} {LY} (R)-BINAP {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (R)-BINAP {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID634876
Beilstein Registry Number4914062
Reaxys-RN4914062
Merck Number1223
InChIInChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
LabNetwork Molecule IDLN00154548
MDL NumberMFCD00010805
CAS Number76189-55-4
Canonical SMILESC1(C=CC=C2)=C2C(C3=C(C=CC=C4)C4=CC=C3P(C5=CC=CC=C5)C6=CC=CC=C6)=C(P(C7=CC=CC=C7)C8=CC=CC=C8)C=C1
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. BINAP
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. BINAP
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Ligands
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Phosphine
  2. 96-6950 Takasago BINAP Ligand Kit

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