Benzeneselenol 苯硒醇

CAS 645-96-5 MFCD00000001

化学结构图

645-96-5
SMILES: [SeH]c1ccccc1

化学属性

Mol. FormulaC6H6Se
Mol. Weight157.07
Refractive index1.6160 to 1.6190
Density1.479 g/mL at 25 °C(lit.)
Boiling Point71-72 °C at 18 mmHg
Flash Point70°C(lit.)
TSCAYes
Stability对空气敏感
Appearance liquid 无色恶臭油状液体。沸点183.6℃，57-59℃（1.07kPa），折光率1.6156，相对密度1.479。

别名和识别编码

Chemical NameBenzeneselenol
MDL NumberMFCD00000001
CAS Number645-96-5
Reaxys-RN385715
Beilstein Registry Number6(4)1777
PubChem Substance ID6327608
EC Number211-457-2
Synonym Benzeneselenol {LY} Benzeneselenol {} {LY} Benzeneselenol {} {} {LY} Benzeneselenol {} {} {} {LY} Benzeneselenol {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzeneselenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation苯硒醇
InChIKeyWDODWFPDZYSKIA-UHFFFAOYSA-N
LabNetwork Molecule IDLN01740663
InChIInChI=1S/C6H5Se/c7-6-4-2-1-3-5-6/h1-5H
Canonical SMILESC1=CC=C(C=C1)[SeH]
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Selenium Compounds

相关文献及参考

  • Short: III/35C4
  • For reactions of phenylselenol and its anion, see Diphenyl­ diselenide, A13919.
  • Short: III/35G
  • {

安全信息

UN Number UN3440 3440 UN 2810 6.1/PG 2
Signal word Danger {} {} {} {TCI}
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P304+P340
  • P304+P340+P311
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H301 Toxic if swallowed 吞食有毒
  • H331 Toxic if inhaled 吸入中毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
GHS Symbol
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S20/21 When using do not eat, drink or smoke 使用时，不得进食，饮水或吸烟；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R50/53
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Hazard Codes T,N
Packing GroupIII
Storage condition 2-8°C {LY} 2-8°C Air Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1

其他信息

  • MOL 文件:645-96-5.mol
  • Sigma Aldrich:645-96-5(sigmaaldrich)
  • TCI Shanghai:苯硒酚 Benzeneselenol,>;95.0%(GC)(645-96-5)
  • 上游原料:溴苯 --> 硒
  • 敏感性:Air Sensitive
  • 5-苯基-1，3，4-恶二唑-2-硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 B2105 苯硒酚 Benzeneselenol 5G 1450元 2010/06/21 123520010 5-苯基-1，3，4-恶二唑-2-硫醇 Phenylselenol 98% 1 GR 553元 2010/06/21 123520100 5-苯基-1，3，4-恶二唑-2-硫醇 Phenylselenol 98% 10 GR 3570元
  • 方法一:用干燥的氢气置换反应系统的空气，使溴苯和镁在绝对乙醚中反应制成苯基溴化镁，然后在搅拌回流下加入干燥硒粉。将混合物倾入碎冰中，加浓盐酸反应。反应物分层后取有机相蒸除乙醚，残余物减压蒸馏收集57-59℃（1.07kPa）馏分，得苯硒酚。
  • color:gold-yellow
  • F:10-23
  • Acros Organics:苯硒酚 Phenylselenol, 98%(645-96-5)
  • 5-苯基-1，3，4-恶二唑-2-硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2105 苯硒酚 Benzeneselenol 5G 1590元 2010/06/21 123520010 5-苯基-1，3，4-恶二唑-2-硫醇 Phenylselenol 98% 1 GR 553元 2010/06/21 123520100 5-苯基-1，3，4-恶二唑-2-硫醇 Phenylselenol 98% 10 GR 3570元
  • Alfa Aesar:苯硒醇,90+% Phenylselenol, 90+%(645-96-5)
  • 用途一:用于合成反应。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Selenium Compounds 硒化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Selenium Compounds 硒化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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