N,N'-Bis(salicylidene)ethylenediamine cobalt(II) N,N′-二(亚水杨基)乙二亚胺钴(II)

CAS 14167-18-1 MFCD00000009

化学结构图

14167-18-1
SMILES: C1CN=CC2=CC=CC=C2O[Co]OC2=CC=CC=C2C=N1 |c:6,16,t:2,21|

化学属性

Mol. FormulaC16H14CoN2O2
Mol. Weight325.23
TSCAYes
Density1.422

别名和识别编码

Chemical NameN,N'-Bis(salicylidene)ethylenediamine cobalt(II)
MDL NumberMFCD00000009
CAS Number14167-18-1
Reaxys-RN4172037
PubChem Substance ID87575841
Synonym Salcomine N,N'-Bis(salicylidene)ethylenediaminecobalt(II) N,N′-双水杨醛缩乙二胺 钴(II) 盐 Co(salen) salcomine Salcomine, N,N′-Disalicylidene-ethylenediamine cobalt(II) salt, Co(SALEN)2, Ethylenebis(salicylimine) cobalt(II) salt N,N'-Bis(salicylidene)ethylenediamine cobalt(II) monohydrate N,N-bis(salicylidene)ethylene-diiminocobalt (II) Cobalt, [2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II); [Bis(salicylidene)ethylenediaminato]cobalt; [N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II); [N,N'-Bis(salicylidene)ethylenediaminato]cobalt; [N,N'-Disalicylideneethylenediamine]cobalt; [N,N'-Ethylenebis(salicylaldehyde iminato)]cobalt(II) Co(SALEN)2 Bis(salicylaldehyde)ethylenediiminecobalt(II) 双水杨酰胺乙基钴
EC Number238-012-5
Beilstein Registry Number4172037
Chemical Name TranslationN,N′-二(亚水杨基)乙二亚胺钴(II)
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分类

  • {uni_hamburg}
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt Catalysts
  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt

相关文献及参考

  • Fieser 2 ,360 / Fieser 3 ,245 / Fieser 6 ,507 / Fieser 7 ,316 / Fieser 12 ,429
  • Corp MSDS 1 (1), 448:A / RegBook 1 (2), 3117:G / Sax 6 , 502 / Structure Index 1 , 493:C:7
  • Short: III/10b Title: Structure Data of Organic Crystals: C 16 ... C 168 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10b Year: 1985 ISBN: 3-540-13932-X ISBN: 978-3-540-13932-4 Internet Resource: DOI:10.1007/b19985 RefComment: XIX,652 pages. Hardcover
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSGG0590000
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H316 Causes mild skin irritation 会轻微的刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S24 Avoid contact with skin 避免皮肤接触；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
WGK Germany3
GHS Symbol
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 390 mg/m3/5.5H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - structural or functional change in trachea
   or bronchi
   Lungs, Thorax, or Respiration - chronic pulmonary edema
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   AMRL** Aerospace Medical Research Laboratory Report.  (Aerospace Technical
   Div., Air Force Systems Command, Wright-Patterson Air Force Base, OH 45433)
   Volume(issue)/page/year: TR-74-78,1974

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cobalt Catalysis 钴催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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