Aluminum Acetylacetonate 三乙酰丙酮铝

CAS 13963-57-0 MFCD00000013

化学结构图

13963-57-0
SMILES: CC(=O)/C=C(/C)\O[Al](O/C(/C)=C\C(C)=O)O/C(/C)=C\C(C)=O

化学属性

Mol. FormulaC15H21AlO6
Mol. Weight324.31
Density1.27
Boiling Point315
Melting Point193.0 to 198.0 deg-C
TSCAYes
Solubility2.5 G/L (20 ºC)
Flash Point314-316°C
Stability对湿度敏感
Appearance white pwdr.

别名和识别编码

Chemical NameAluminum Acetylacetonate
CAS Number13963-57-0
EC Number237-741-6
Beilstein Registry Number4157942
MDL NumberMFCD00000013
Reaxys-RN4157942
PubChem Substance ID87561900
Synonym 2,4-乙酰丙酮铝 Al(acac)3 Al(acac)3, Aluminum 2,4-pentanedionate Al(acac)3; Aluminum 2,4-pentanedionate Alu Aluminum acetylacetonate Aluminum complex of acetylacetone Aluminum triacetylacetonate Aluminum tris(acetylacetonate) Aluminum trisacetoacetonate Aluminum, tris(2,4-pentanedionato)- Aluminumacetylacetonate Dotite Al Tris(2,4-pentanedione)aluminum Tris(acetylaceton Tris(acetylacetonate)aluminum Tris(acetylacetonato)-aluminium(III) Tris(acetylacetonato)aluminum aluminum, tris(2,4-pentanedionato-O,o')-, (OC-6-11)- tris(pentane-2,4-dionato-O,O')aluminium 三乙酰丙酮铝
Chemical Name Translation三乙酰丙酮铝
Wiswesser Line NotationD6O-AL-O BDJ D1 F1 B-& BD6O-AL-O BDJ D1 F1 B-&BD6O-AL-O BDJ D1 F1
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分类

  • {SNA} Aluminum, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SNA} Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {SNA} Aluminum, Catalysis and Inorganic Chemistry, Chemical Synthesis
  • {uni_hamburg} no charge; ketone; 4fragments; ionic

产品应用

  • 催化剂。交联剂。通过化学螯合作用提高油墨、涂料、胶水、树脂等高分子材料的性能。 使用方法:用于溶剂型丙烯酸、环氧、聚酯、聚氨酯压敏胶中起固化交联作用,不含-OH、-COOH、-NH2等必须对其进行预处理。添加量为1.5-2‰(具体用量请实验后确定),在产品合成完成后,温度降至70℃以下添加已稀释的乙酰丙酮铝,搅拌几分钟即可.

相关文献及参考

  • Short: III/20a
  • Short: III/5b
  • Beilstein: 1,IV,3668
  • Short: IV/1a

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBD2230000
UN Number 3467
Hazard statements
  • H301+H311+H331
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H300 Fatal if swallowed 吞食致命
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes 6.1 T
Packing GroupII
Storage condition 密封保存。
Hazard Class6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02376

其他信息

  • 能溶于醇和醚,难溶于水,不溶于石油醚。在1毫米汞柱压力、100℃时缓慢升华,156℃很快升华。
  • HazardClass:6.1

系列性分类


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