Ethylmagnesium bromide 乙基溴化镁

CAS 925-90-6 MFCD00000043

化学结构图

925-90-6
SMILES: CC[Mg]Br

化学属性

Mol. FormulaC2H5BrMg
Mol. Weight133.27
Density1.02
Melting Point-116.3°
TSCAYes
Boiling Point34.6°
Flash Point-40 ºC
Stability对光、空气、热和湿度敏感
Appearance liq. dark brown liq.

别名和识别编码

Chemical NameEthylmagnesium bromide
CAS Number925-90-6
EC Number213-127-3
Beilstein Registry Number3587203
Reaxys-RN3910290
PubChem Substance ID101914
MDL NumberMFCD00000043
Synonym Bromoethylmagnesium ETHYLMAGNESIUM BROMIDE ETHYLMAGNESIUM BROMIDE 1M SOLUTION IN TERT-BUTYL METHYL ETHER ETHYLMAGNESIUM BROMIDE SOLUTION, ETHYLMAGNESIUM BROMIDE SOLUTION, ~3 M IN ETHYLMAGNESIUM BROMIDE, 1.0M SOLUTION IN TERT-BUTYL METHYL ETHER ETHYLMAGNESIUM BROMIDE, 1.0M SOLUTION IN TETRAHYDROFURAN ETHYLMAGNESIUM BROMIDE, 3.0M SOLUTION IN DIETHYL ETHER Ethyl magnesium bromide Ethyl-magnesium-bromide Ethylmagnesium Ethylmagnesium Bromide 1.0 M In Methyl t-Butyl Ether Ethylmagnesium Bromide 1.0 M In Tetrahydrofuran Ethylmagnesium Bromide 3.0 M In Diethyl Ether Ethylmagnesium Bromide 3.0 M In n-Butyl Ether Ethylmagnesium bromide Ethylmagnesium bromide, 1M solution in THF Ethylmagnesium bromide, 3M in Diethy
Chemical Name Translation乙基溴化镁
LabNetwork Molecule IDLN00162752
InChIInChI=1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q-1;;+2/p-1
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分类

  • {SA} Alkyl, Chemical Synthesis, Grignard Reagents,
  • {SNA} 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Acids & Bases, Alkyl, Bases, Chemical Synthesis,
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} 12 Principles Aligned Products,
  • {SNA} Alkyl,

相关文献及参考

  • Short: III/35C4
  • Short: III/35D5
  • Beilstein: 4,656

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number 3399
Hazard statements
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupI
Storage condition 25°C可能会结晶，摇匀即可 water-free area Air & Moisture Sensitive 充氩保存
Hazard Codes 4.3 F+,C,F F+;C F,C
Hazard Class4.3/3
Restrict 危险品

其他信息

  • 乙基溴化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0134 乙基溴化镁(39%的乙醚溶液,约3mol/L) Ethylmagnesium Bromide (39% in Ethyl Ether, ca. 3mol/L) 250G 800元 2014/06/02 E0497 乙基溴化镁(13%的四氢呋喃溶液,约1mol/L) Ethylmagnesium Bromide (13% in Tetrahydrofuran, ca. 1mol/L) 250G 320元 2010/06/21 347298000 乙基溴化镁 Ethylmagnesium bromide , 3M in diethyl ether, AcroSeal® 800 ML 1832元
  • Acros Organics:乙基溴化镁 Ethylmagnesium bromide, ca. 3.2M solution in 2-Methyl-THF; AcroSeal?(925-90-6)
  • Alfa Aesar:乙基溴化镁,3M乙醚溶液,在氩气保护下储存在ChemSeal密封瓶中 Ethylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles(925-90-6)
  • Sigma Aldrich:925-90-6(sigmaaldrich)
  • F:1-3-10
  • 敏感性:Air & Moisture Sensitive
  • MOL 文件:925-90-6.mol
  • TCI Shanghai:乙基溴化镁(13%的四氢呋喃溶液,约1mol/L) Ethylmagnesium Bromide (13% in Tetrahydrofuran, ca. 1mol/L)(925-90-6)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Organic Acids - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. L - Alphabetic
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. P - Alphabetic
  5. PON - PT - P
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl
  1. Functional Group 官能团索引
  2. organomagnesium compound
  1. Grignard
  2. Magnesium

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