Hexylmagnesium Bromide Solution 正己基溴化镁
CAS 3761-92-0 MFCD00000046
化学结构图
SMILES: CCCCCC[Mg]Br
化学属性
| Mol. Formula | C6H13BrMg |
|---|---|
| Mol. Weight | 189.38 |
| Density | 0.965 |
| Flash Point | -40 °C |
| Stability | 对湿度和空气敏感 |
别名和识别编码
| Chemical Name | Hexylmagnesium Bromide Solution |
|---|---|
| CAS Number | 3761-92-0 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 3535624 |
| MDL Number | MFCD00000046 |
| Reaxys-RN | 6117705 |
| PubChem Substance ID | 4184939 |
| Synonym | HEXYLMAGNESIUM BROMIDE 己基溴化镁 溶液 |
| Chemical Name Translation | 正己基溴化镁 |
| InChIKey | SFXUWNMDTWQSHE-UHFFFAOYSA-M |
| InChI | InChI=1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q-1;;+2/p-1 |
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分类
- Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
- {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
- {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
相关文献及参考
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R12 Extremely flammable 极端易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P222 Do not allow contact with air. 不要与空气接触。
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P305+P351+P338
- P303+P361+P353
- P403+P233
- P305+P351+P338+P310
- P301+P330+P331+P310
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H302 Harmful if swallowed 吞食有害
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
其他信息
- F:1-3-10
- MOL 文件:3761-92-0.mol
- TCI Shanghai:己基溴化镁(20%的四氢呋喃溶液,约1mol/L) Hexylmagnesium Bromide (20% in Tetrahydrofuran, ca. 1mol/L)(3761-92-0)
- 己基溴化镁(20%的四氢呋喃溶液,约1MOL/L)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0821 己基溴化镁(20%的四氢呋喃溶液,约1mol/L) Hexylmagnesium Bromide (20% in Tetrahydrofuran, ca. 1mol/L) 250G 500元
- Sigma Aldrich:3761-92-0(sigmaaldrich)
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