Triethylbromosilane 三乙基溴硅烷

CAS 1112-48-7 MFCD00000049

化学结构图

1112-48-7
SMILES: CC[Si](Br)(CC)CC

化学属性

Mol. FormulaC6H15BrSi
Mol. Weight195
Refractive index1.4550 to 1.4590
Boiling Point163°C(lit.)
Density1.135 g/mL at 20 °C(lit.)
Flash Point53°C(lit.)
Melting Point-50°C
Stability对湿度敏感

别名和识别编码

Chemical NameTriethylbromosilane
MDL NumberMFCD00000049
CAS Number1112-48-7
Synonym {uni_hamburg} Triethylbromosilane triethylbromosilane TRIETHYLBROMOSILANE Silane, bromotriethyl- 三乙基溴硅烷 bromotriethylsilane
PubChem Substance ID70680
EC Number214-191-5
Beilstein Registry Number1732870
Chemical Name Translation三乙基溴硅烷
InChIKeyUCKORWKZRPKRQE-UHFFFAOYSA-N
Reaxys-RN1732870
LabNetwork Molecule IDLN01281284
InChIInChI=1S/C6H15BrSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
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分类

  • Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Beil. 4 ,IV,4050
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool fo

安全信息

GHS Symbol
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
WGK Germany3
Hazard Codes C
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R10 Flammable 易燃
Precautionary statements
  • P303+P361+P353+P310+P363
  • P241+P242+P243
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P301+P330+P331+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word Danger
UN Number 2920 UN 2920 8/PG 2
Storage condition 储存温度 2-8°C ,充氩储存
Hazard Class8/3
Packing GroupII

其他信息

  • Sigma Aldrich:1112-48-7(sigmaaldrich)
  • F:10-21
  • MOL 文件:1112-48-7.mol
  • TSCA:Yes

系列性分类


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