Bis(4-Bromophenyl) Ether 双(4-溴苯基)醚

CAS 2050-47-7 MFCD00000095

化学结构图

2050-47-7
SMILES: Brc1ccc(Oc2ccc(Br)cc2)cc1

化学属性

Mol. FormulaC12H8Br2O
Mol. Weight328.00
Density1.413
Melting Point56-60 °C
TSCAYes
Boiling Point338-340 °C at 760 mmHg
Flash Point338-340°C

别名和识别编码

Chemical NameBis(4-Bromophenyl) Ether
MDL NumberMFCD00000095
CAS Number2050-47-7
EC Number218-090-7
Beilstein Registry Number2050738
Reaxys-RN2050738
PubChem Substance ID16305
Synonym 4,4'-Oxybis(bromobenzene) {LY} 4,4'-Oxybis(bromobenzene) {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxybis(bromobenzene) {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation双(4-溴苯基)醚
Wiswesser Line NotationER DOR DE
LabNetwork Molecule IDLN00199921
InChIInChI=1S/C12H8Br2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H
Canonical SMILESBrC1=CC=C(OC2=CC=C(Br)C=C2)C=C1
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, B, BA - BH, Bromo, Chemical Class, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, Flame Retardants, Halogenated, ISO 22032, Method and Regulation Specific
  • Alphabetic, Analytical Standards, Analytical/Chromatography, B, BA - BH, Bromo, Chemical Class, European Community: ISO, DIN and DL 152, Flame retardants, Halogenated, ISO 22032, Method Specific

相关文献及参考

  • Short: III/35D2
  • Short: III/20b
  • Beilstein:6(4)1048

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S29 Do not empty into drains 不要排入下水道；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R38 Irritating to skin 刺激皮肤
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R50/53
  • R33 Danger of cumulative effects 有累积作用的危险
Precautionary statements
RTECSKN0175000
Hazard Codes F,Xn,N
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number UN 1262 3/PG 2 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,16,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

  • 可燃性危险特性:可燃; 燃烧产生有毒溴化物烟雾
  • 下游产品:4,4'-二羟基二苯醚
  • 毒性分级:高毒
  • 图谱信息:4,4'-二溴二苯醚(2050-47-7)红外图谱(IR1) 4,4'-二溴二苯醚(2050-47-7)核磁图( 1 HNMR) 4,4'-二溴二苯醚(2050-47-7)红外图谱(IR2) 4,4'-二溴二苯醚(2050-47-7)核磁图( 13 CNMR) 4,4'-二溴二苯醚(2050-47-7)质谱(MS)
  • MSDS 信息:Bis(4-bromophenyl) ether(2050-47-7).msds
  • 4,4'-二溴二苯醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0834 双(4-溴苯基)醚 Bis(4-bromophenyl) Ether 25G 820元 2010/06/21 402290250 4,4'-二溴二苯醚 Bis(4-bromophenyl) ether 96% 25 GR 1352元 2010/05/25 16684 双(4-溴苯基)醚,99+% Bis(4-bromophenyl) ether, 99+% 5g 266元
  • Alfa Aesar:双(4-溴苯基)醚,99+% Bis(4-bromophenyl) ether, 99+%(2050-47-7)
  • Sigma Aldrich:2050-47-7(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 用途一:用作有机合成中间体
  • Acros Organics:4,4-二溴联苯醚 Bis(4-bromophenyl) ether, 96%(2050-47-7)
  • 急性毒性:口服-大鼠 LD: >;500 毫克/公斤; 腹腔-小鼠 LD50: 125 毫克/公斤
  • TCI Shanghai:4,4'-二溴苯醚 Bis(4-bromophenyl) Ether,>;97.0%(GC)(2050-47-7)
  • MOL 文件:2050-47-7.mol
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C13 to C14 - Ethers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Bromo 溴化物

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